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Issue 29, 2016
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Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

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Abstract

The all-cis isomer of 1,2,3,4-tetrafluorocyclopentane is prepared and characterised by NMR and X-ray crystallography and the experimental structure compared with theory. The structure has a similarly high polarity to all-cis tetrafluorocyclohexanes despite the increased conformational flexibility of a cyclopentane.

Graphical abstract: Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

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Publication details

The article was received on 12 Feb 2016, accepted on 10 Mar 2016 and first published on 11 Mar 2016


Article type: Communication
DOI: 10.1039/C6CC01348A
Citation: Chem. Commun., 2016,52, 5116-5119
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    Polar alicyclic rings: synthesis and structure of all cis-1,2,3,4-tetrafluorocyclopentane

    Z. Fang, N. Al-Maharik, A. M. Z. Slawin, M. Bühl and D. O'Hagan, Chem. Commun., 2016, 52, 5116
    DOI: 10.1039/C6CC01348A

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