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Issue 26, 2016
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Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

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Abstract

An unstable diiron(II,II) complex possessing O2 binding ability at low temperature was encapsulated and stabilized in an ammonium-type ionic liquid layer polymerized on an electrode. The encapsulated complex revealed catalytic reactivity for four-electron reduction of O2 at an ambient temperature in aqueous solution.

Graphical abstract: Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

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Publication details

The article was received on 14 Dec 2015, accepted on 19 Feb 2016 and first published on 01 Mar 2016


Article type: Communication
DOI: 10.1039/C5CC10263D
Citation: Chem. Commun., 2016,52, 4780-4783
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    Immobilization of a non-heme diiron complex encapsulated in an ammonium-type ionic liquid layer modified on an Au electrode: reactivity of the electrode for O2 reduction

    T. Kitagawa, J. Nishino, T. Inomata, T. Ozawa, Y. Funahashi and H. Masuda, Chem. Commun., 2016, 52, 4780
    DOI: 10.1039/C5CC10263D

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