Issue 95, 2015
From the journal:

Chemical Communications

Design of a Brønsted acid with two different acidic sites: synthesis and application of aryl phosphinic acid–phosphoric acid as a Brønsted acid catalyst†

N. Momiyama,*a   T. Narumibc  and  M. Terada*cd  

* Corresponding authors

a Institute for Molecular Science, and SOKENDAI (the Graduate School for Advanced Studies), Okazaki, Aichi 444-8787, Japan
E-mail: momiyama@ims.ac.jp

b Cooperative Education Program of IMS with Tohoku University, Japan

c Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan
E-mail: mterada@m.tohoku.ac.jp

d Analytical Center for Giant Molecules, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan

Abstract

A Brønsted acid with two different acidic sites, aryl phosphinic acid–phosphoric acid, has been synthesized. Its catalytic performance was assessed in the hetero-Diels–Alder reaction of aldehyde hydrates with Danishefsky's diene, achieving high reaction efficiency.

Graphical abstract: Design of a Brønsted acid with two different acidic sites: synthesis and application of aryl phosphinic acid–phosphoric acid as a Brønsted acid catalyst

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Article information

DOI
https://doi.org/10.1039/C5CC06787A
Article type
Communication
Submitted
12 Aug 2015
Accepted
24 Sep 2015
First published
24 Sep 2015

Chem. Commun., 2015,51, 16976-16979

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Design of a Brønsted acid with two different acidic sites: synthesis and application of aryl phosphinic acid–phosphoric acid as a Brønsted acid catalyst

N. Momiyama, T. Narumi and M. Terada, Chem. Commun., 2015, 51, 16976 DOI: 10.1039/C5CC06787A

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