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Issue 28, 2015
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Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

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Abstract

Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 sāˆ’1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells.

Graphical abstract: Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

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Publication details

The article was received on 05 Feb 2015, accepted on 02 Mar 2015 and first published on 04 Mar 2015


Article type: Communication
DOI: 10.1039/C5CC01107H
Citation: Chem. Commun., 2015,51, 6172-6174
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    Nickel phosphine catalysts with pendant amines for electrocatalytic oxidation of alcohols

    C. J. Weiss, E. S. Wiedner, J. A. S. Roberts and A. M. Appel, Chem. Commun., 2015, 51, 6172
    DOI: 10.1039/C5CC01107H

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