The protocol of the reductive amination of aromatic aldehydes using ammonium formate and Hantzsch ester is described. It is a mild, convenient, acid- and catalyst-free system applied for the synthesis of both symmetric and asymmetric aromatic secondary amines.
P. Zhao, X. Zhou, J. Dai and H. Xu, Org. Biomol. Chem., 2014, 12, 9092 DOI: 10.1039/C4OB01590H
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