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Issue 80, 2014
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High thermal stability of block copolymer-capped Au and Cu nanoparticles

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Abstract

Producing solution-based metal nanoparticles that do not agglomerate at elevated temperatures remains challenging. We show that thermally stable Au and Cu nanoparticles can be prepared using polystyrene–poly(4-vinylpyridine) diblock copolymers as capping agents. These materials remain stable when their solutions are subjected to prolonged heating up to 160 °C for more than 48 h. These conditions are sufficient for applications in most wet chemical processes and reactions.

Graphical abstract: High thermal stability of block copolymer-capped Au and Cu nanoparticles

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Publication details

The article was received on 27 Jun 2014, accepted on 12 Aug 2014 and first published on 12 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC04937C
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 11919-11921
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    High thermal stability of block copolymer-capped Au and Cu nanoparticles

    I. I. Perepichka, M. A. Mezour, D. F. Perepichka and R. B. Lennox, Chem. Commun., 2014, 50, 11919
    DOI: 10.1039/C4CC04937C

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