Issue 35, 2014
From the journal:

Chemical Communications

Transition-metal-free, visible-light induced cyclization of arylsulfonyl chlorides with 2-isocyanobiphenyls to produce phenanthridines†

Lijun Gu,*a   Cheng Jin,b   Jiyan Liu,a   Hongyan Dinga  and  Baomin Fana  

* Corresponding authors

a Key Laboratory of Chemistry in Ethnic Medicinal Resources, State Ethnic Affairs Commission & Ministry of Education, Yunnan University of Nationalities, Kunming, Yunnan, China
E-mail: gulijun2005@126.com

b New United Group Company Limited, Changzhou, Jiangsu, China

Abstract

6-Aryl substituted phenanthridines were synthesized via a visible-light-catalyzed cyclization of 2-isocyanobiphenyls with arylsulfonyl chlorides under oxidant-free and transition-metal-free conditions. This transformation represents an efficient and attractive synthetic utilization of arylsulfonyl chlorides.

Graphical abstract: Transition-metal-free, visible-light induced cyclization of arylsulfonyl chlorides with 2-isocyanobiphenyls to produce phenanthridines

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Article information

DOI
https://doi.org/10.1039/C4CC01487A
Article type
Communication
Submitted
26 Feb 2014
Accepted
12 Mar 2014
First published
27 Mar 2014

Chem. Commun., 2014,50, 4643-4645

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Transition-metal-free, visible-light induced cyclization of arylsulfonyl chlorides with 2-isocyanobiphenyls to produce phenanthridines

L. Gu, C. Jin, J. Liu, H. Ding and B. Fan, Chem. Commun., 2014, 50, 4643 DOI: 10.1039/C4CC01487A

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