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Issue 76, 2014
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Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons

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Abstract

A low-coordinate iron(I) species can reversibly reduce pyridine, either by one electron to give a new C–C bond, or by two electrons to give a pyridine-derived bridge with an unprecedented μ-η13 binding mode.

Graphical abstract: Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons

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Publication details

The article was received on 16 Jul 2014, accepted on 04 Aug 2014 and first published on 11 Aug 2014


Article type: Communication
DOI: 10.1039/C4CC05495D
Author version available: Download Author version (PDF)
Citation: Chem. Commun., 2014,50, 11114-11117
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    Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons

    R. A. Lewis, K. C. MacLeod, B. Q. Mercado and P. L. Holland, Chem. Commun., 2014, 50, 11114
    DOI: 10.1039/C4CC05495D

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