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Issue 22, 2012
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Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

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Abstract

A variety of internally N-alkylated N-confused porphyrins were prepared in a stepwise manner through the protection of the reactive peripheral nitrogen atom. NH-Tautomerism in N-confused porphyrins was found to be regulated by N-alkylation, which enabled us to obtain discrete information on two important NH-tautomers of an N-confused porphyrin.

Graphical abstract: Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

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Publication details

The article was received on 19 Feb 2012, accepted on 03 Apr 2012 and first published on 03 Apr 2012


Article type: Paper
DOI: 10.1039/C2OB25351H
Citation: Org. Biomol. Chem., 2012,10, 4367-4374
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    Regulation of NH-tautomerism in N-confused porphyrin by N-alkylation

    M. Toganoh, T. Yamamoto, T. Hihara, H. Akimaru and H. Furuta, Org. Biomol. Chem., 2012, 10, 4367
    DOI: 10.1039/C2OB25351H

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