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Issue 10, 2012
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Novel TiO2–Pt@SiO2 nanocomposites with high photocatalytic activity

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Abstract

This article reports a facile and controllable two-step method to construct TiO2–Pt@SiO2 nanocomposites. TiO2 nanoparticles (NPs), with small size and high surface energy, were synthesized by a solvothermal reaction process. The TiO2–Pt@SiO2 nanocomposites were fabricated by a reverse micro-emulsion method. SiO2 shell coated NPs were adopted for further photocatalytic reaction. Because of their small size and high surface energy, TiO2@SiO2 and TiO2–Pt@SiO2 nanocomposites show higher photocatalytic activity than commercial Degussa P25. Compared with TiO2@SiO2, TiO2–Pt@SiO2nanocomposites have improved photocatalytic activity due to the Pt induced spatial separation of electrons and holes. The silica shells not only maintain the structure of the nanocomposites but also prevent their aggregation during the photocatalytic reactions, which is highly important for the good durability of the photocatalyst. This strategy is simple, albeit efficient, and can be extended to the synthesis of other composites of noble metals. It has opened a new window for the construction of hetero-nanocomposites with high activity and durability, which would serve as excellent models in catalytic systems of both theoretical and practical interest.

Graphical abstract: Novel TiO2–Pt@SiO2 nanocomposites with high photocatalytic activity

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Publication details

The article was received on 03 Mar 2012, accepted on 15 Mar 2012 and first published on 20 Mar 2012


Article type: Paper
DOI: 10.1039/C2NR30523B
Citation: Nanoscale, 2012,4, 3242-3247
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    Novel TiO2–Pt@SiO2 nanocomposites with high photocatalytic activity

    H. Wu, L. Sun, H. Zhou and C. Yan, Nanoscale, 2012, 4, 3242
    DOI: 10.1039/C2NR30523B

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