Jump to main content
Jump to site search

Issue 33, 2012
Previous Article Next Article

Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry

Author affiliations

Abstract

ESI-MS based methodology for the rapid reactivity screening of [PW11O39RhCl]5− and [PW11O39Ir(H2O)]4− toward various metalation-intended substrates (reagents with an activated C–H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh–R (R = malonate, phenylacetate, CH3, Ph, ferrocenyl) and Ir–R (R = CH3) bonds is reported.

Graphical abstract: Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry

Back to tab navigation

Supplementary files

Publication details

The article was received on 22 Mar 2012, accepted on 18 Jun 2012 and first published on 19 Jun 2012


Article type: Communication
DOI: 10.1039/C2DT30655G
Citation: Dalton Trans., 2012,41, 9889-9892
  •   Request permissions

    Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry

    M. N. Sokolov, S. A. Adonin, P. L. Sinkevich, C. Vicent, D. A. Mainichev and V. P. Fedin, Dalton Trans., 2012, 41, 9889
    DOI: 10.1039/C2DT30655G

Search articles by author

Spotlight

Advertisements