Issue 4, 2013

Trans [O[double bond, length as m-dash]ReV–OH] core stabilised by chelating N-heterocyclic dicarbene ligands

Abstract

Three Re(V) N-heterocyclic carbene complexes [ReO(OH)(LMe)2][PF6]1.4[ReO4]0.6, [ReO(OH)(LiPr)2][PF6]1.4[ReO4]0.6 and [ReO(OH)(LBn)2][PF6]1.3[ReO4]0.7 (LMe = 1,1′-methylene-bis(3-methylimidazole-2-ylidene); LiPr = 1,1′-methylene-bis(3-isopropylimidazole-2-ylidene) and LBn = 1,1′-methylene-bis(3-benzylimidazole-2-ylidene)) with trans oxo and hydroxo at axial positions have been synthesized.

Graphical abstract: Trans [O [[double bond, length as m-dash]] ReV–OH] core stabilised by chelating N-heterocyclic dicarbene ligands

Supplementary files

Article information

Article type
Communication
Submitted
26 Jul 2012
Accepted
06 Nov 2012
First published
07 Nov 2012

Dalton Trans., 2013,42, 871-873

Trans [O[double bond, length as m-dash]ReV–OH] core stabilised by chelating N-heterocyclic dicarbene ligands

R. Lum, H. Zhang, W. Zhang, S. Bai, J. Zhao and T. S. A. Hor, Dalton Trans., 2013, 42, 871 DOI: 10.1039/C2DT31681A

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