A stable sulfone based electrolyte for high performance rechargeable Li–O2 batteries

Dan Xu; Zhong-li Wang; Ji-jing Xu; Lei-lei Zhang; Li-min Wang; Xin-bo Zhang

doi:10.1039/C2CC36815C

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Chemical Communications

Issue 95, 2012

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A stable sulfone based electrolyte for high performance rechargeable Li–O₂ batteries

Dan Xu,^a Zhong-li Wang,^a Ji-jing Xu,^a Lei-lei Zhang,^a^b Li-min Wang^a and Xin-bo Zhang*^a

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State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China
E-mail: xbzhang@ciac.jl.cn ;
Fax: +86 431 85262235 ;
Tel: +86 431 85262235

University of Chinese Academy of Sciences, Beijing, China

Chem. Commun., 2012,48, 11674-11676

DOI: 10.1039/C2CC36815C
Received 19 Sep 2012, Accepted 12 Oct 2012
First published online 12 Oct 2012

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A tetramethylene sulfone based electrolyte was used in rechargeable Li–O₂ batteries for the first time. Without a catalyst, superior battery performances were successfully obtained, and desired lithium peroxide (Li₂O₂) dominates the discharge product.

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Dan Xu
Zhong-li Wang
Ji-jing Xu
Lei-lei Zhang
Li-min Wang
Xin-bo Zhang

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A stable sulfone based electrolyte for high performance rechargeable Li–O₂ batteries