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Issue 43, 2012
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Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine

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Abstract

The dimetallic [M2(bpy)2(NO3)2](NO3)2 moieties (M = Pd(II) or Pt(II)) react preferentially at the pyrazolyl end of the pyridyl-pyrazole ligand, giving rise to dimetallic corners. Subsequently, the dimetallic corner building blocks featuring two pyridine donors are coordinated by monometallic [M(bpy)(NO3)2] moieties (M = Pd(II) or Pt(II)) to form homo- or hetero-metallomacrocycles.

Graphical abstract: Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine

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Publication details

The article was received on 18 Feb 2012, accepted on 23 Mar 2012 and first published on 27 Mar 2012


Article type: Communication
DOI: 10.1039/C2CC31234D
Citation: Chem. Commun., 2012,48, 5343-5345
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    Programmable self-assembly of homo- or hetero-metallomacrocycles using 4-(1H-pyrazolyl-4-yl)pyridine

    J. Tong, S. Yu and H. Li, Chem. Commun., 2012, 48, 5343
    DOI: 10.1039/C2CC31234D

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