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Issue 43, 2012
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Asymmetric aldol reaction via memory of chirality

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Abstract

Asymmetric aldol reactions of α-amino acid derivatives via memory of chirality were developed. Chiral oxazolidones with contiguous tetra- and trisubstituted chiral centers were obtained in 78–94% ee by the asymmetric aldol reaction followed by intramolecular acylation.

Graphical abstract: Asymmetric aldol reaction via memory of chirality

  • This article is part of the themed collection: Chirality
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Publication details

The article was received on 27 Feb 2012, accepted on 03 Apr 2012 and first published on 03 Apr 2012


Article type: Communication
DOI: 10.1039/C2CC31447A
Citation: Chem. Commun., 2012,48, 5346-5348
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    Asymmetric aldol reaction via memory of chirality

    H. Watanabe, T. Yoshimura, S. Kawakami, T. Sasamori, N. Tokitoh and T. Kawabata, Chem. Commun., 2012, 48, 5346
    DOI: 10.1039/C2CC31447A

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