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Issue 2, 2011
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Conjugated polymers/semiconductor nanocrystals hybrid materials—preparation, electrical transport properties and applications

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Abstract

This critical review discusses specific preparation and characterization methods applied to hybrid materials consisting of π-conjugated polymers (or oligomers) and semiconductor nanocrystals. These materials are of great importance in the quickly growing field of hybrid organic/inorganic electronics since they can serve as active components of photovoltaic cells, light emitting diodes, photodetectors and other devices. The electronic energy levels of the organic and inorganic components of the hybrid can be tuned individually and thin hybrid films can be processed using low cost solution based techniques. However, the interface between the hybrid components and the morphology of the hybrid directly influences the generation, separation and transport of charge carriers and those parameters are not easy to control. Therefore a large variety of different approaches for assembling the building blocks—conjugated polymers and semiconductor nanocrystals—has been developed. They range from their simple blending through various grafting procedures to methods exploiting specific non-covalent interactions between both components, induced by their tailor-made functionalization. In the first part of this review, we discuss the preparation of the building blocks (nanocrystals and polymers) and the strategies for their assembly into hybrid materials' thin films. In the second part, we focus on the charge carriers' generation and their transport within the hybrids. Finally, we summarize the performances of solar cells using conjugated polymer/semiconductor nanocrystals hybrids and give perspectives for future developments.

Graphical abstract: Conjugated polymers/semiconductor nanocrystals hybrid materials—preparation, electrical transport properties and applications

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Publication details

The article was received on 14 Jun 2010, accepted on 06 Oct 2010 and first published on 10 Dec 2010


Article type: Review Article
DOI: 10.1039/C0NR00403K
Citation: Nanoscale, 2011,3, 446-489
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    Conjugated polymers/semiconductor nanocrystals hybrid materials—preparation, electrical transport properties and applications

    P. Reiss, E. Couderc, J. De Girolamo and A. Pron, Nanoscale, 2011, 3, 446
    DOI: 10.1039/C0NR00403K

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