Issue 12, 2011
From the journal:

Dalton Transactions

Proton-induced reactivities of ruthenium azido complexes: the first example of boron–carbon bond formation by methylene insertion into a B–H bond†

Yih-Hsing Lo,*a   Han-Gung Chena  and  Ting Shen Kuob  

* Corresponding authors

a Department of Natural Science, Taipei Municipal University of Education, Taipei, Republic of China
E-mail: yhlo@tmue.edu.tw
Fax: (886)-2-2389-7641

b Instrumentation Center, College of Science, National Taiwan Normal University, Taipei, Taiwan, Republic of China

Abstract

Whereas the reaction of Tp(PhCN)(PPh3)Ru–N3 {Tp = HB(pz)3, pz = pyrazolyl} with CH3I in CH2Cl2 led to the cationic ruthenium methyleneimine complex [Tp(PPh3)(PhCN)Ru(NH[double bond, length as m-dash]CH2)]I, the analogous reaction with HCl gave rise to the ruthenium chloride complex containing a methyl tris(pyrazolyl)borate ligand MeTp(PPh3)(PhCN)RuCl, as a result of the highly unusual methylene insertion into a B–H bond of the Tp ligand.

Graphical abstract: Proton-induced reactivities of ruthenium azido complexes: the first example of boron–carbon bond formation by methylene insertion into a B–H bond

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Article information

DOI
https://doi.org/10.1039/C0DT01091J
Article type
Communication
Submitted
23 Aug 2010
Accepted
31 Jan 2011
First published
15 Feb 2011

Dalton Trans., 2011,40, 2711-2715

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Proton-induced reactivities of ruthenium azido complexes: the first example of boron–carbon bond formation by methylene insertion into a B–H bond

Y. Lo, H. Chen and T. S. Kuo, Dalton Trans., 2011, 40, 2711 DOI: 10.1039/C0DT01091J

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