Issue 3, 1991
From the journal:

Journal of the Chemical Society, Chemical Communications

Does the rhodium-catalysed addition of perhaloalkanes to alkenes (i.e. the Kharasch reaction) proceed via an oxidative-addition mechanism?: the crystal structure of RhBr(CCl3)Cl(CO)(PMe3)2

Christopher J. Cable,   Harry Adams,   Neil A. Bailey,   John Crosby  and  Colin White  

Abstract

Evidence is presented to show that rhodium(I)-catalysed Kharasch reactions may proceed via oxidative-addition of the perhalocarbon to the Rh followed by stepwise transfer to a coordinated alkene.

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Article information

DOI
https://doi.org/10.1039/C39910000165
Article type
Paper

J. Chem. Soc., Chem. Commun., 1991, 165-166

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Does the rhodium-catalysed addition of perhaloalkanes to alkenes (i.e. the Kharasch reaction) proceed via an oxidative-addition mechanism?: the crystal structure of RhBr(CCl3)Cl(CO)(PMe3)2

C. J. Cable, H. Adams, N. A. Bailey, J. Crosby and C. White, J. Chem. Soc., Chem. Commun., 1991, 165 DOI: 10.1039/C39910000165

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