Pig liver esterase catalysed hydrolysis of diester (1) with dimethyl sulphoxide as cosolvent in buffered solutions gave optically pure monoester (2) which was further transformed to the (R)-proline related ester (4) by radical decarboxylation.
F. Björkling, J. Boutelje, M. Hjalmarsson, K. Hult and T. Norin, J. Chem. Soc., Chem. Commun., 1987, 1041 DOI: 10.1039/C39870001041
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