This study proposes a dual-tunable terahertz (THz) perfect absorber that modulates its properties using optical pumping and temperature control.
A kinetic resolution of unprotected binols and biphenols has been successfully realized through chiral FLP-catalyzed dehydrogenative coupling with hydrosilanes.
The intramolecular α-C(sp3)–H silylation of alkyl sulphides with hydrosilanes has been achieved for the first time by half-sandwich rare-earth catalysts, affording a new family of heterocyclic [1,3]-thiasilolanes.
The dynamic field of the CO2 Reduction Reaction (CO2RR) seeks to harness CO2 as a sustainable carbon source or energy carrier. This review explores CO2 reduction into formaldehyde (HCHO) or acetal-type compounds using various CO2RR systems.
A novel half-sandwich Co(dppbsa) ([Co]) was synthesized and employed for the catalytic N,N-dimethylation of nitroaromatics with CO2 and hydrosilane. The same catalyst also enabled the highly efficient reduction of nitroaromatics to aromatic amines.