This study proposes a dual-tunable terahertz (THz) perfect absorber that modulates its properties using optical pumping and temperature control.
A kinetic resolution of unprotected binols and biphenols has been successfully realized through chiral FLP-catalyzed dehydrogenative coupling with hydrosilanes.
A novel half-sandwich Co(dppbsa) ([Co]) was synthesized and employed for the catalytic N,N-dimethylation of nitroaromatics with CO2 and hydrosilane. The same catalyst also enabled the highly efficient reduction of nitroaromatics to aromatic amines.
An NHC–zinc alkyl complex catalyzed CDC reaction of a wide range of primary and secondary amines and hydrosilanes to yield a substantial quantity of corresponding aminosilanes with good chemoselectivity at room temperature is reported.
Readily available Cu(II) organometallic catalyst precursors allow the N-methylation of amines with CO2 and hydrosilanes to be efficiently performed.