Tetraoxolene-bridged rare-earth complexes: a radical-bridged dinuclear Dy single-molecule magnet

William R. Reed, Maja A. Dunstan, Robert W. Gable, Wasinee Phonsri, Keith S. Murray, Richard A. Mole and Colette Boskovic

Dalton Trans., 2019, 48, 15635
DOI: 10.1039/C9DT01320B

Heterobimetallic uranyl(vi) alkoxides of lanthanoids: formation through simple ligand exchange

Dennis Grödler, Martin L. Weidemann, Andreas Lichtenberg, Tobias Greven, Robin Nickstadt, Malek Haydo, Mathias Wickleder, Axel Klein, Dirk Johrendt, Sanjay Mathur, Markus Zegke and Aida Raauf

Chem. Commun., 2022, 58, 835
DOI: 10.1039/D1CC05444A

How does chemistry contribute to circular economy in nuclear energy systems to make them more sustainable and ecological?

Koichiro Takao

Dalton Trans., 2023, 52, 9866
DOI: 10.1039/D3DT01019H

The effect of iron binding on uranyl(v) stability

Radmila Faizova, Sarah White, Rosario Scopelliti and Marinella Mazzanti

Chem. Sci., 2018, 9, 7520
DOI: 10.1039/C8SC02099J

New zinc complexes derived from “self-adaptable” acyclic diiminodipyrromethanes as potent catalysts for the reduction of curing temperature of bisphenol-A/F benzoxazines

Shiva K. Loke, Eswar Pagadala, S. Devaraju, V. Srinivasadesikan and Ravi K. Kottalanka

RSC Adv., 2020, 10, 36275
DOI: 10.1039/D0RA07837A

Extended dipyrrin ligands: candidates for optical metal ion detection under competitive conditions

S. Guski, M. Albrecht, T. Willms, M. Albrecht, T. Nabeshima, F. Pan, R. Puttreddy and K. Rissanen

Chem. Commun., 2017, 53, 3213
DOI: 10.1039/C7CC00672A

Synthesis and complexes of a constrained-cavity Schiff-base dipyrrin macrocycle

Karlotta van Rees and Jason B. Love

Dalton Trans., 2021, 50, 1610
DOI: 10.1039/D1DT00175B

Controlled and sequential single-electron reduction of the uranyl dication

Tom J. N. Obey, Gary S. Nichol and Jason B. Love

Dalton Trans., 2024, 53, 16229
DOI: 10.1039/D4DT02367F

The synthesis and characterization of the octahedral CoIII complex of a pyrrolopyrrolizine derivative formed with dicyanovinylene-bis-(meso-aryl)dipyrrin

Ji-Young Shin

RSC Adv., 2021, 11, 2315
DOI: 10.1039/D0RA09452H

Differential uranyl(v) oxo-group bonding between the uranium and metal cations from groups 1, 2, 4, and 12; a high energy resolution X-ray absorption, computational, and synthetic study

Markus Zegke, Xiaobin Zhang, Ivan Pidchenko, Johann A. Hlina, Rianne M. Lord, Jamie Purkis, Gary S. Nichol, Nicola Magnani, Georg Schreckenbach, Tonya Vitova, Jason B. Love and Polly L. Arnold

Chem. Sci., 2019, 10, 9740
DOI: 10.1039/C8SC05717F

Synthesis of pyrrolo[3′,2′:4,5][1,3]diazepino[2,1,7-cd]pyrrolizine derivatives from dicyanovinylene-bis(meso-aryl)dipyrrin

Ji-Young Shin

RSC Adv., 2019, 9, 40031
DOI: 10.1039/C9RA08850D

Schiff base thorium(iv) and uranium(iv) chloro complexes: synthesis, substitution and oxidation chemistry

Brian C. Stobbe, Douglas R. Powell and Robert K. Thomson

Dalton Trans., 2017, 46, 4888
DOI: 10.1039/C7DT00580F

Double uranium oxo cations derived from uranyl by borane or silane reduction

Bradley E. Cowie, Gary S. Nichol, Jason B. Love and Polly L. Arnold

Chem. Commun., 2018, 54, 3839
DOI: 10.1039/C8CC00341F

F-element metalated dipyrrins: synthesis and characterization of a family of uranyl bis(dipyrrinate) complexes

Duer Bolotaulo, Alejandro Metta-Magaña and Skye Fortier

Dalton Trans., 2017, 46, 3284
DOI: 10.1039/C7DT00150A

Quantitative UO bond activation in uranyl complexes via silyl radical transfer

Leyla R. Valerio, Brett M. Hakey, William W. Brennessel and Ellen M. Matson

Chem. Commun., 2022, 58, 11244
DOI: 10.1039/D2CC04424B

Redox-induced reversible P–P coupling in a uranium complex

Wei Fang, Ambre Carpentier, Xiong Sun, Yue Zhao, Laurent Maron and Congqing Zhu

Chem. Commun., 2021, 57, 12175
DOI: 10.1039/D1CC04765E

Utility of redox-active ligands for reversible multi-electron transfer in uranyl(vi) complexes

Tomoyuki Takeyama, Satoru Tsushima and Koichiro Takao

Inorg. Chem. Front., 2023, 10, 4028
DOI: 10.1039/D3QI00189J

Solid-state structural elucidation and electrochemical analysis of uranyl naphthylsalophen

Julie E. Niklas, Emily E. Hardy and Anne E. V. Gorden

Chem. Commun., 2018, 54, 11693
DOI: 10.1039/C8CC05242E

Density functional theory (DFT) calculations of VI/V reduction potentials of uranyl coordination complexes in non-aqueous solutions

Krishnamoorthy Arumugam and Neil A. Burton

Phys. Chem. Chem. Phys., 2019, 21, 3227
DOI: 10.1039/C8CP05412F

Controlling mixed-valence states of pyridyldiimino-bis(o-phenolato) ligand radical in uranyl(vi) complexes

Tomoyuki Takeyama, Satoru Tsushima and Koichiro Takao

Dalton Trans., 2024, 53, 16671
DOI: 10.1039/D4DT01821D

Dipyrrin based metal complexes: reactivity and catalysis

Stéphane A. Baudron

Dalton Trans., 2020, 49, 6161
DOI: 10.1039/D0DT00884B

Ni(II) Complexes of the Redox-Active Bis(2-aminophenyl)dipyrrin: Structural, Spectroscopic, and Theoretical Characterization of Three Members of an Electron Transfer Series

Jules Moutet, Christian Philouze, Amaury du Moulinet d’Hardemare, Nicolas Leconte and Fabrice Thomas

Inorg. Chem., 2017, 56, 6380
DOI: 10.1021/acs.inorgchem.7b00433

Observations regarding the synthesis and redox chemistry of heterobimetallic uranyl complexes containing Group 10 metals

Emily R. Mikeska, Natalie M. Lind, Alexander C. Ervin, Celine Khalife, Joseph P. Karnes and James D. Blakemore

Radiochimica Acta, 2024, 112, 149
DOI: 10.1515/ract-2023-0237

Molybdenum(VI) bis-imido Complexes of Dipyrromethene Ligands

Jan Locher, Fabian A. Watt, Adam G. Neuba, Roland Schoch, Dominik Munz and Stephan Hohloch

Inorg. Chem., 2020, 59, 9847
DOI: 10.1021/acs.inorgchem.0c01051

Distinguishing Desirable and Undesirable Reactions in Multicomponent Systems for Redox Activation of the Uranyl Ion

Emily R. Mikeska, Małgorzata Z. Makoś, Grant A. Arehart, Vassiliki-Alexandra Glezakou and James D. Blakemore

Inorg. Chem., 2025, 64, 5827
DOI: 10.1021/acs.inorgchem.4c02753

A Series of AnVIO22+ Complexes (An = U, Np, Pu) with N3O2-Donating Schiff-Base Ligands: Systematic Trends in the Molecular Structures and Redox Behavior

Tomoyuki Takeyama, Satoru Tsushima, Robert Gericke, Tamara M. Duckworth, Peter Kaden, Juliane März and Koichiro Takao

Inorg. Chem., 2025, 64, 1313
DOI: 10.1021/acs.inorgchem.4c04185

Synthesis and Characterization of Pyridine Dipyrrolide Uranyl Complexes

Brett M. Hakey, Dylan C. Leary, Lauren M. Lopez, Leyla R. Valerio, William W. Brennessel, Carsten Milsmann and Ellen M. Matson

Inorg. Chem., 2022, 61, 6182
DOI: 10.1021/acs.inorgchem.2c00348

Uranyl to Uranium(IV) Conversion through Manipulation of Axial and Equatorial Ligands

Nicola L. Bell, Brian Shaw, Polly L. Arnold and Jason B. Love

J. Am. Chem. Soc., 2018, 140, 3378
DOI: 10.1021/jacs.7b13474

Synthesis and Characterization of a Water Stable Uranyl(V) Complex

Radmila Faizova, Rosario Scopelliti, Anne-Sophie Chauvin and Marinella Mazzanti

J. Am. Chem. Soc., 2018, 140, 13554
DOI: 10.1021/jacs.8b07885

Disproportionation of the Uranyl(V) Coordination Complexes in Aqueous Solution through Outer-Sphere Electron Transfer

Krishnamoorthy Arumugam and Neil A. Burton

Inorg. Chem., 2021, 60, 18832
DOI: 10.1021/acs.inorgchem.1c02575

Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides

Polly L. Arnold, Bradley E. Cowie, Markéta Suvova, Markus Zegke, Nicola Magnani, Eric Colineau, Jean‐Christophe Griveau, Roberto Caciuffo and Jason B. Love

Angew Chem Int Ed, 2017, 56, 10775
DOI: 10.1002/anie.201705197

The role of uranium–arene bonding in H2O reduction catalysis

Dominik P. Halter, Frank W. Heinemann, Laurent Maron and Karsten Meyer

Nature Chem, 2018, 10, 259
DOI: 10.1038/nchem.2899

Ligand‐Supported Facile Conversion of Uranyl(VI) into Uranium(IV) in Organic and Aqueous Media

Radmila Faizova, Farzaneh Fadaei‐Tirani, Rizlan Bernier‐Latmani and Marinella Mazzanti

Angew Chem Int Ed, 2020, 59, 6756
DOI: 10.1002/anie.201916334

Evidence for Uranium(VI/V) Redox Supported by 2,2′-Bipyridyl-6,6′-dicarboxylate

Emily R. Mikeska, Alexander C. Ervin, Kaihua Zhang, Gabriel M. Benitez, Samuel M. R. Powell, Allen G. Oliver, Victor W. Day, Marco Caricato, Chelsea G. Comadoll and James D. Blakemore

Inorg. Chem., 2023, 62, 16131
DOI: 10.1021/acs.inorgchem.3c02397

Progress in Nonaqueous Molecular Uranium Chemistry: Where to Next?

Stephen T. Liddle

Inorg. Chem., 2024, 63, 9366
DOI: 10.1021/acs.inorgchem.3c04533

Control of Ligand pKa Values Tunes the Electrocatalytic Dihydrogen Evolution Mechanism in a Redox-Active Aluminum(III) Complex

Tobias J. Sherbow, James C. Fettinger and Louise A. Berben

Inorg. Chem., 2017, 56, 8651
DOI: 10.1021/acs.inorgchem.7b00230

Ligand-Based Redox: Catalytic Applications and Mechanistic Aspects

Kirti Singh, Abhishek Kundu and Debashis Adhikari

ACS Catal., 2022, 12, 13075
DOI: 10.1021/acscatal.2c02655

Synthesis and Characterization of Water Stable Uranyl(V) Complexes

Radmila Faizova, Farzaneh Fadaei‐Tirani, Anne‐Sophie Chauvin and Marinella Mazzanti

Angewandte Chemie, 2021, 133, 8308
DOI: 10.1002/ange.202016123

Recent developments in metal dipyrrin complexes: Design, synthesis, and applications

Roop Shikha Singh, Rajendra Prasad Paitandi, Rakesh Kumar Gupta and Daya Shankar Pandey

Coordination Chemistry Reviews, 2020, 414, 213269
DOI: 10.1016/j.ccr.2020.213269

Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [UVIO2]2+

Bradley E. Cowie, Jamie M. Purkis, Jonathan Austin, Jason B. Love and Polly L. Arnold

Chem. Rev., 2019, 119, 10595
DOI: 10.1021/acs.chemrev.9b00048

Role of the Meso Substituent in Defining the Reduction of Uranyl Dipyrrin Complexes

Karlotta van Rees, Thayalan Rajeshkumar, Laurent Maron, Stephen Sproules and Jason B. Love

Inorg. Chem., 2022, 61, 20424
DOI: 10.1021/acs.inorgchem.2c03048

Ligand and Metal Based Multielectron Redox Chemistry of Cobalt Supported by Tetradentate Schiff Bases

Julie Andrez, Valentin Guidal, Rosario Scopelliti, Jacques Pécaut, Serge Gambarelli and Marinella Mazzanti

J. Am. Chem. Soc., 2017, 139, 8628
DOI: 10.1021/jacs.7b03604

Axially Symmetric U−O−Ln‐ and U−O−U‐Containing Molecules from the Control of Uranyl Reduction with Simple f‐Block Halides

Polly L. Arnold, Bradley E. Cowie, Markéta Suvova, Markus Zegke, Nicola Magnani, Eric Colineau, Jean‐Christophe Griveau, Roberto Caciuffo and Jason B. Love

Angewandte Chemie, 2017, 129, 10915
DOI: 10.1002/ange.201705197

Uranyl‐Bound Tetra‐Dentate Non‐Innocent Ligands: Prediction of Structure and Redox Behaviour Using Density Functional Theory

Krishnamoorthy Arumugam and Neil A. Burton

ChemPhysChem, 2019, 20, 1869
DOI: 10.1002/cphc.201900301

Syntheses and solid-state structures of two cofacial (bis)dipyrrin dichromium complexes in different charge states

Kurtis Carsch, Shelby E. Elder, Dilek K. Dogutan, Daniel G. Nocera, Junyu Yang, Shao-Liang Zheng, Timothy Daniel and Theodore A. Betley

Acta Crystallogr C Struct Chem, 2021, 77, 161
DOI: 10.1107/S2053229621001388

Bonding Interactions in Uranyl α-Diimine Complexes: A Spectroscopic and Electrochemical Study of the Impacts of Ligand Electronics and Extended Conjugation

Julie E. Niklas, Katherine M. Hunter and Anne E. V. Gorden

Inorg. Chem., 2019, 58, 15088
DOI: 10.1021/acs.inorgchem.9b01695

Two-Electron Oxidative Atom Transfer at a Homoleptic, Tetravalent Uranium Complex

Natalie T. Rice, Karl McCabe, John Bacsa, Laurent Maron and Henry S. La Pierre

J. Am. Chem. Soc., 2020, 142, 7368
DOI: 10.1021/jacs.0c02693

Triggering Redox Activity in a Thiophene Compound: Radical Stabilization and Coordination Chemistry

Massimiliano Curcio, James R. Pankhurst, Stephen Sproules, Dimitri Mignard and Jason B. Love

Angew Chem Int Ed, 2017, 56, 7939
DOI: 10.1002/anie.201703576

Synthesis and Characterization of Isostructural Th(IV) and U(IV) Pyridine Dipyrrolide Complexes

Leyla R. Valerio, Brett M. Hakey, Dylan C. Leary, Erin Stockdale, William W. Brennessel, Carsten Milsmann and Ellen M. Matson

Inorg. Chem., 2024, 63, 9610
DOI: 10.1021/acs.inorgchem.3c04391

Interaction with Simple Monopyridinecarboxylic Ligands Revealing Unexpected Structural Types of Uranyl Halides

Grigory Andreev, Nina Budantseva and Aleksander Fedoseev

Inorg. Chem., 2020, 59, 15583
DOI: 10.1021/acs.inorgchem.0c02718

Triggering Redox Activity in a Thiophene Compound: Radical Stabilization and Coordination Chemistry

Massimiliano Curcio, James R. Pankhurst, Stephen Sproules, Dimitri Mignard and Jason B. Love

Angewandte Chemie, 2017, 129, 8047
DOI: 10.1002/ange.201703576

Ligand‐Supported Facile Conversion of Uranyl(VI) into Uranium(IV) in Organic and Aqueous Media

Radmila Faizova, Farzaneh Fadaei‐Tirani, Rizlan Bernier‐Latmani and Marinella Mazzanti

Angewandte Chemie, 2020, 132, 6822
DOI: 10.1002/ange.201916334

Understanding the Effect of pH on the Solubility and Aggregation Extent of Humic Acid in Solution by Combining Simulation and the Experiment

Tu Lan, Peng Wu, Ziyi Liu, Martin Stroet, Jiali Liao, Zhifang Chai, Alan E. Mark, Ning Liu and Dongqi Wang

Environ. Sci. Technol., 2022, 56, 917
DOI: 10.1021/acs.est.1c05938

Effects of Substituents on the Molecular Structure and Redox Behavior of Uranyl(V/VI) Complexes with N3O2-Donating Schiff Base Ligands

Tomoyuki Takeyama, Satoru Tsushima and Koichiro Takao

Inorg. Chem., 2021, 60, 11435
DOI: 10.1021/acs.inorgchem.1c01449

Radical‐Type Reactivity and Catalysis by Single‐Electron Transfer to or from Redox‐Active Ligands

Jarl Ivar van der Vlugt

Chemistry A European J, 2019, 25, 2651
DOI: 10.1002/chem.201802606

Neptunyl Pyrrophen Complexes: Exploring Schiff Base Chemistry with Multidentate Acyclic Ligands and Transuranics

John Ducilon, Aaron D. Nicholas, Robert G. Surbella and Anne E. V. Gorden

Chemistry A European J, 2024
DOI: 10.1002/chem.202402047

Pyridine Diphosphonate Ligand for Stabilization of Tetravalent Uranium and Neptunium in Aqueous Medium under Aerobic Conditions

Parveen Kumar Verma, Bholanath Mahanty, Arunasis Bhattacharyya, Petr I. Matveev, Nataliya E. Borisova, Stepan N. Kalmykov and Prasanta Kumar Mohapatra

Inorg. Chem., 2024, 63, 3348
DOI: 10.1021/acs.inorgchem.3c03840

Di‐μ‐acetato Diuranyl(VI) Complexes withN‐(2‐pyridyl)‐N′‐(5‐R‐salicylidene)hydrazines: Syntheses, Structures, Properties and Extraction Studies

Sabari Ghosh, Sathish Kumar Kurapati, Arpita Ghosh, Ankit Kumar Srivastava and Samudranil Pal

ChemistrySelect, 2018, 3, 4865
DOI: 10.1002/slct.201800940

Radical Relatives: Facile Oxidation of Hetero-Diarylmethene Anions to Neutral Radicals

Massimiliano Curcio, Daniel Henschel, Mareike Hüttenschmidt, Stephen Sproules and Jason B. Love

Inorg. Chem., 2018, 57, 9592
DOI: 10.1021/acs.inorgchem.8b00554

Two-Electron Reduction of a U(VI) Complex with Al(C5Me5)

Robert J. Ward, Iker Del Rosal, Danielle N. Chirdon, Steven P. Kelley, Michael L. Tarlton, Laurent Maron and Justin R. Walensky

Inorg. Chem., 2020, 59, 16137
DOI: 10.1021/acs.inorgchem.0c03036

Fate of Oxidation States at Actinide Centers in Redox‐Active Ligand Systems Governed by Energy Levels of 5 f Orbitals

Tomoyuki Takeyama, Satoru Tsushima, Robert Gericke, Peter Kaden, Juliane März and Koichiro Takao

Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202302702

Structural Characterization and Redox Activity of a Uranyl Dimer and Transition-Metal Complexes of a Tetradentate BIAN Ligand

Julie E. Niklas, Byron H. Farnum, John D. Gorden and Anne E. V. Gorden

Organometallics, 2017, 36, 4626
DOI: 10.1021/acs.organomet.7b00454

Synthesis, Photophysical and Redox Properties of Highly Stable Radicals of Nickel(II) Bis(2-aminophenyl)-azadipyrromethene

Wanwan Li, Qingbao Gong, Quansheng Zhao, Qinghua Wu, Chuang Niu, Lijuan Jiao and Erhong Hao

Inorg. Chem., 2025, 64, 9114
DOI: 10.1021/acs.inorgchem.5c00662

A Hexagonal Bipyramidal Uranyl(V) Single-Ion Magnet Showing Finger-Type Photoluminescence

Pei-Yu Liao, Hao-Ran Xing, Yi-Ling Zhong, Xi-Nan Xu, Peng-Xu Lu, Shang-Da Jiang, Cheng-Hui Li, Jun-Liang Liu, Richard A. Layfield and Ming-Liang Tong

J. Am. Chem. Soc., 2025, 147, 22714
DOI: 10.1021/jacs.5c04541

Synthesis and Characterization of Water Stable Uranyl(V) Complexes

Radmila Faizova, Farzaneh Fadaei‐Tirani, Anne‐Sophie Chauvin and Marinella Mazzanti

Angew Chem Int Ed, 2021, 60, 8227
DOI: 10.1002/anie.202016123

Exploring the Redox Properties of Bench-Stable Uranyl(VI) Diamido–Dipyrrin Complexes

Karlotta van Rees, Emma K. Hield, Ambre Carpentier, Laurent Maron, Stephen Sproules and Jason B. Love

Inorg. Chem., 2022, 61, 3249
DOI: 10.1021/acs.inorgchem.1c03744

Unprecedented biological evaluation of Zn(II) complexes supported by “Self-adjustable” acyclic diiminodipyrromethane Schiff’s bases: DFT, molecular docking; biological activity studies

Shiva Krishna Loke, Eswar Pagadala, Venkatesan Srinivasadesikan, Rex Jeya Rajkumar Samdavid Thanapaul, T. Pooventhiran, Renjith Thomas, G. Naganjaneyulu and Ravi K. Kottalanka

Inorganic Chemistry Communications, 2021, 133, 108936
DOI: 10.1016/j.inoche.2021.108936

Bis(dipyrrinato)zinc(II) Complex Chiroptical Wires: Exfoliation into Single Strands and Intensification of Circularly Polarized Luminescence

Risa Aoki, Ryojun Toyoda, Julius F. Kögel, Ryota Sakamoto, Jatish Kumar, Yasutaka Kitagawa, Koji Harano, Tsuyoshi Kawai and Hiroshi Nishihara

J. Am. Chem. Soc., 2017, 139, 16024
DOI: 10.1021/jacs.7b07077

Ligand-Centered Triplet Diradical Supported by a Binuclear Palladium(II) Dipyrrindione

Clayton J. Curtis, Andrei V. Astashkin, Jeanet Conradie, Abhik Ghosh and Elisa Tomat

Inorg. Chem., 2021, 60, 12457
DOI: 10.1021/acs.inorgchem.1c01691