Issue 2, 2022

Non-fullerene acceptors with direct and indirect hexa-fluorination afford >17% efficiency in polymer solar cells

Abstract

The rational molecular design of non-fullerene acceptors (NFAs) in organic solar cells (OSCs) can profoundly influence the photovoltaic (OPV) performance. To date, NFA fluorination has proven beneficial to cell performance. However, there is a lack of comprehensive understanding of how various fluorination modalities influence film morphology, carrier mobility, molecular packing, other structural properties, electronic structure, exciton separation, and charge transport, that determine ultimate cell efficiency. Here, we compare two types of end group (EG) fluorination patterns on Y6-based A-DAD-A cores, resulting in highly efficient NFAs: direct skeletal fluorination (BTF) and indirect trifluoromethyl fluorination (BTFM). These two patterns induce distinctive behaviors in the active layer blends with a chlorinated donor polymer D18-Cl and the additive, 1-chloronaphthalene, affording high PCE values of 17.30% (BTF + additive) and 17.10% (BTFM, no-additive). The BTFvs.BTFM OSC performance trends can be correlated with diffraction-derived differences in molecular packing. Density functional theory (DFT) reveals remarkably low internal reorganization energies and high electronic coupling between NFA dimers, greater and more numerous than in other NFAs reported to date, thus providing extended 3D charge transport networks in the thin film crystalline domains. Transient absorption spectroscopy reveals that hole transfer from the acceptor to the donor occurs in <300 fs and that photoexcited carriers persist for hundreds of ns in each blend film. The contrasting role of the additive in BTF and BTFM cells is further clarified by recombination dynamics analysis using in situ photocurrent and impedance spectroscopy. Overall, this work provides guidance for developing new NFAs via direct and indirect fluorination strategies for high efficiency OSCs.

Graphical abstract: Non-fullerene acceptors with direct and indirect hexa-fluorination afford >17% efficiency in polymer solar cells

Supplementary files

Article information

Article type
Paper
Submitted
14 Okt 2021
Accepted
22 Dis 2021
First published
22 Dis 2021

Energy Environ. Sci., 2022,15, 645-659

Author version available

Non-fullerene acceptors with direct and indirect hexa-fluorination afford >17% efficiency in polymer solar cells

G. Li, L. Feng, S. Mukherjee, L. O. Jones, R. M. Jacobberger, W. Huang, R. M. Young, R. M. Pankow, W. Zhu, N. Lu, K. L. Kohlstedt, V. K. Sangwan, M. R. Wasielewski, M. C. Hersam, G. C. Schatz, D. M. DeLongchamp, A. Facchetti and T. J. Marks, Energy Environ. Sci., 2022, 15, 645 DOI: 10.1039/D1EE03225A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements