Issue 33, 2021

Recent advances in synthesis and crystal structures of metal pentazolate salts

Abstract

Pentazole is the last member of the azole family. As a five-membered ring constructed from nitrogen, a pentazole skeleton is a good nitrogen-donor ligand, which possesses great potential to prepare intriguing multidimensional structures. In recent years, a series of metal pentazolate salts have been synthesized, which have attracted immense attention due to their interesting crystal structures. In this study, an overview of all the reported metal pentazolate salts is provided; furthermore, the key issues to be solved and future prospects in this field are also discussed.

Graphical abstract: Recent advances in synthesis and crystal structures of metal pentazolate salts

Article information

Article type
Highlight
Submitted
12 Mey 2021
Accepted
15 Jul 2021
First published
15 Jul 2021

CrystEngComm, 2021,23, 5551-5559

Recent advances in synthesis and crystal structures of metal pentazolate salts

H. Xia, W. Zhang, Y. Cao and Q. Zhang, CrystEngComm, 2021, 23, 5551 DOI: 10.1039/D1CE00635E

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