Volume 217, 2019

Photoelectron-photofragment coincidence studies of I3 using an electrospray ionization source and a linear accelerator

Abstract

Photoelectron-photofragment coincidence (PPC) spectroscopy is used to examine the dissociative photodetachment (DPD) of I3. The high beam energy PPC spectrometer for complex anions couples an electrospray ionization source, a hexapole accumulation ion trap and a linear accelerator to produce fast beams of I3 (M = 381 amu) anions, the heaviest system studied to date. Following photodetachment, the photoelectron and up to three photofragments are recorded in coincidence yielding a kinematically complete picture of the DPD dynamics at beam energies of 11 keV and 21 keV. Photodetachment leads to the production of stable I3, two-body DPD, as well as evidence for two- and three-body photodissociation. DPD is found to occur predominantly via the first excited A state, with some contributions from highly excited vibrational levels in the neutral ground state. With the ions thermalized to 298 K in the hexapole trap, there are significant contributions from vibrational hot bands. Three-body photodissociation at 4.66 eV is found to occur preferentially via a charge-symmetric process to form I + I + I. In the future this method will be applied to other polyatomic systems with a large molecular mass, including multiply charged anions and complex clusters, in concert with a cryogenically cooled hexapole trap to reduce thermal effects.

Graphical abstract: Photoelectron-photofragment coincidence studies of I3− using an electrospray ionization source and a linear accelerator

Associated articles

Article information

Article type
Paper
Submitted
30 Nov 2018
Accepted
17 Jan 2019
First published
23 Eph 2019

Faraday Discuss., 2019,217, 203-219

Author version available

Photoelectron-photofragment coincidence studies of I3 using an electrospray ionization source and a linear accelerator

J. A. Gibbard and R. E. Continetti, Faraday Discuss., 2019, 217, 203 DOI: 10.1039/C8FD00216A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements