Issue 4, 2018

Improved capacitive deionization by using 3D intercalated graphene sheet–sphere nanocomposite architectures

Abstract

Capacitive deionization (CDI) is an alternative water purification technology offering a suitable way to obtain drinkable water. Electrode materials are quite crucial for the deionization efficiency. Here, for the first time, a straightforward and cost-effective approach is developed to prepare 3D intercalated graphene sheet–sphere nanocomposite architectures as high-performance CDI electrodes by using graphene oxide and [Ni2(EDTA)] as precursors. 3D graphene nanospheres between graphene sheets inhibit the restacking of graphene layers. Significantly, the as-prepared 3D mesoporous graphene sheet–sphere nanocomposite architectures possess high specific surface area and suitable pore size distribution. By using 3D mesoporous graphene sheet–sphere nanocomposite architectures as an electrode, an ultrahigh electrosorptive capacity of 22.09 mg g−1 is achieved in a 500 mg L−1 NaCl solution at 1.2 V, and the salt removal percentage of the obtained electrodes is around 90%. Furthermore, the electrodes present good deionization stability and regeneration performance. This work also offers a promising solution to develop highly effective electrode materials in the CDI process for brackish and sea water desalination.

Graphical abstract: Improved capacitive deionization by using 3D intercalated graphene sheet–sphere nanocomposite architectures

Supplementary files

Article information

Article type
Paper
Submitted
23 Dis 2017
Accepted
22 Feb 2018
First published
23 Feb 2018

Environ. Sci.: Nano, 2018,5, 980-991

Improved capacitive deionization by using 3D intercalated graphene sheet–sphere nanocomposite architectures

Z. U. Khan, T. Yan, L. Shi and D. Zhang, Environ. Sci.: Nano, 2018, 5, 980 DOI: 10.1039/C7EN01246B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements