Issue 50, 2018
From the journal:

Chemical Communications

Proton and ammonia intercalation into layered iron chalcogenides†

Xiuquan Zhou, ORCID logo ab   Brandon Wilfong,ab   Sz-Chian Liou,c   Halyna Hodovanets,b   Craig M. Brown ORCID logo d  and  Efrain E. Rodriguez ORCID logo *ab  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA
E-mail: efrain@umd.edu

b Center for Nanophysics and Advanced Materials, Department of Physics, University of Maryland, College Park, MD 20742, USA

c AIM Lab, Maryland NanoCenter, University of Maryland, College Park, MD 20742, USA

d NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA

Abstract

Structurally related to the iron-based superconductors, two new intercalated iron chalcogenides (H0.5NH3)Fe2Ch2 where Ch = S, Se have been prepared. By topochemical conversion, the protons were exchanged by lithium to form (Li0.5NH3)Fe2Ch2. Hydrogen bonding plays a significant role in the guest–host interactions of these intercalated phases.

Graphical abstract: Proton and ammonia intercalation into layered iron chalcogenides

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C8CC02436G
Article type
Communication
Submitted
27 Mas 2018
Accepted
30 Eph 2018
First published
02 Mey 2018

Chem. Commun., 2018,54, 6895-6898

Author version available


Download author version (PDF)

Permissions

Request permissions

Proton and ammonia intercalation into layered iron chalcogenides

X. Zhou, B. Wilfong, S. Liou, H. Hodovanets, C. M. Brown and E. E. Rodriguez, Chem. Commun., 2018, 54, 6895 DOI: 10.1039/C8CC02436G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements