Issue 6, 2011
From the journal:

RSC Advances

Chelation-assisted palladium-catalyzed high regioselective heck diarylation reaction of 9-allyl-9H-purine: synthesis of 9-(3,3-diaryl-allyl)-9H-purines†

Hai-Ming Guo,*a   Wei-Hao Rao,a   Hong-Ying Niu,b   Li-Li Jiang,a   Lei Liang,a   Yang Zhanga  and  Gui-Rong Qu*a  

* Corresponding authors

a College of Chemistry and Environmental Science, Key Laboratory of Green Chemical Media and Reactions of Ministry of Education, Henan Normal University, Xinxiang, Henan, China
E-mail: guohm518@hotmail.com, quguir@sina.com
Fax: 86 373 3329276
Tel: 86 373 3329255

b School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang, China

Abstract

A Pd-catalyzed high regioselective diarylation of 9-allyl-9H-purinevia chelation-assisted Heck reaction is developed. There were two different types of β-H in the allyl substrate, while the two aryl groups are exclusively introduced to the terminal of the olefins.

Graphical abstract: Chelation-assisted palladium-catalyzed high regioselective heck diarylation reaction of 9-allyl-9H-purine: synthesis of 9-(3,3-diaryl-allyl)-9H-purines

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1RA00410G
Article type
Communication
Submitted
06 Jul 2011
Accepted
13 Aga 2011
First published
23 Sep 2011

RSC Adv., 2011,1, 961-963

Permissions

Request permissions

Chelation-assisted palladium-catalyzed high regioselective heck diarylation reaction of 9-allyl-9H-purine: synthesis of 9-(3,3-diaryl-allyl)-9H-purines

H. Guo, W. Rao, H. Niu, L. Jiang, L. Liang, Y. Zhang and G. Qu, RSC Adv., 2011, 1, 961 DOI: 10.1039/C1RA00410G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements