Issue 42, 2011
From the journal:

Chemical Communications

Simple routes to bulky silyl-substituted acetylideligands and examples of V(iii), Fe(ii), and Mn(ii) complexes†

Gereon M. Yee,a   Kristin Kowolik,a   Shuhei Manabe,a   James C. Fettingera  and  Louise A. Berben*a  

* Corresponding authors

a Department of Chemistry, University of California, Davis, CA, USA
E-mail: laberben@ucdavis.edu
Fax: (+1) 530 752 8995
Tel: (+1) 530 752 8475

Abstract

Synthesis of substituted phenylacetylide ligands 2,6-bis(trimethylsilyl)phenylacetylene (H1) and 2-(triphenylsilyl)phenylacteylene (H2) is reported. Ligand 1 supports tetrahedral complexes of V(III), Fe(II), and Mn(II) (3–5). Complexes 3–5 are high-spin and redox active.

Graphical abstract: Simple routes to bulky silyl-substituted acetylide ligands and examples of V(iii), Fe(ii), and Mn(ii) complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C1CC14758G
Article type
Communication
Submitted
02 Aga 2011
Accepted
10 Sep 2011
First published
26 Sep 2011

Chem. Commun., 2011,47, 11680-11682

Permissions

Request permissions

Simple routes to bulky silyl-substituted acetylide ligands and examples of V(III), Fe(II), and Mn(II) complexes

G. M. Yee, K. Kowolik, S. Manabe, J. C. Fettinger and L. A. Berben, Chem. Commun., 2011, 47, 11680 DOI: 10.1039/C1CC14758G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements