Reactions of Ar′CrCrAr′ with N2O or N3(1-Ad): complete cleavage of the Cr–Cr quintuple interaction

Chengbao Ni; Bobby D. Ellis; Gary J. Long; Philip P. Power

doi:10.1039/B901494B

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Reactions of Ar′CrCrAr′ with N₂O or N₃(1-Ad): complete cleavage of the Cr–Cr quintuple interaction†

Chengbao Ni,^a Bobby D. Ellis,^a Gary J. Long^b and Philip P. Power*^a

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* Corresponding authors

^a Department of Chemistry, University of California, Davis, California 95616, USA
E-mail: pppower@ucdavis.edu

^b Department of Chemistry, Missouri University of Science and Technology, University of Missouri, Rolla, Missouri 65409-0010, USA

Abstract

Reaction of Ar′CrCrAr′ (Ar′ = C₆H₃-2,6-(C₆H₃-2,6-Prⁱ₂)₂) with heterocumulene reagents N₂O or N₃(1-Ad) resulted in Ar′Cr(μ-O)₂Cr(O)Ar′ or Ar′Cr(μ₂:η¹,η³-N₃(1-Ad))CrAr′ which have no metal–metal bonding.

This article is part of the themed collection: Philip Power at 65: an icon of organometallic chemistry

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Article information

DOI: https://doi.org/10.1039/B901494B
Article type: Communication
Submitted: 23 Jan 2009
Accepted: 06 Mas 2009
First published: 25 Mas 2009

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Chem. Commun., 2009, 2332-2334

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Reactions of Ar′CrCrAr′ with N₂O or N₃(1-Ad): complete cleavage of the Cr–Cr quintuple interaction

C. Ni, B. D. Ellis, G. J. Long and P. P. Power, Chem. Commun., 2009, 2332 DOI: 10.1039/B901494B

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