Issue 14, 2021

A protecting group–free approach for synthesizing C-glycosides through glycosyl dithiocarbamates

Abstract

The first protection/deprotection-free process for radical C-glycosylation has been achieved through one-step preparable glycosyl dithiocarbamates (GDTCs). The Giese-type reaction and radical allylation of unprotected GDTCs were successfully performed to obtain the corresponding α-C-glycosides stereoselectively under mild reaction conditions.

Graphical abstract: A protecting group–free approach for synthesizing C-glycosides through glycosyl dithiocarbamates

Supplementary files

Article information

Article type
Communication
Submitted
19 Feb 2021
Accepted
17 Mas 2021
First published
18 Mas 2021

Org. Biomol. Chem., 2021,19, 3134-3138

A protecting group–free approach for synthesizing C-glycosides through glycosyl dithiocarbamates

G. Li, M. Noguchi, G. Arisaka, Y. Tanaka and S. Shoda, Org. Biomol. Chem., 2021, 19, 3134 DOI: 10.1039/D1OB00311A

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