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A supramolecular polymer, 3T-DPP, that undergoes photoinduced proton-coupled electron transfer was constructed by means of amidinium-carboxylate salt bridges that serve to link terthiophene electron donors and diketopyrrolopyrrole electron acceptors with a 1 : 1 binding constant of 1.13 × 105 M−1 in N-methyl pyrrolidone.

Graphical abstract: Amidinium–carboxylate salt bridge mediated proton-coupled electron transfer in a donor–acceptor supramolecular system

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