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Abstract | Cited by

An enantioselective C–H functionalization of pyrrole derivatives with diazo compounds has been successfully realized with up to 90% ee by employing dichlorobis(benzonitrile)palladium with an axially chiral bipyridine ligand C3-ACBP as the catalyst. Asymmetric C–H functionalization at the gram scale was also conducted smoothly with good reactivity and enantioselectivity.

Graphical abstract: Enantioselective palladium-catalyzed C–H functionalization of pyrroles using an axially chiral 2,2′-bipyridine ligand

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