Issue 4, 2017

Recyclable 3D printing of vitrimer epoxy

Abstract

3D printing of polymeric materials for various applications has been quickly developed in recent years. In contrast to thermoplastics, 3D printed thermosets, although desirable, are inherently non-recyclable due to their permanently crosslinked networks. As 3D printing is becoming more popular, it is desirable to develop recycling approaches for 3D printed parts in view of increasing polymer wastes. Here, we present a new thermosetting vitrimer epoxy ink and a 3D printing method that can 3D print epoxy into parts with complicated 3D geometries, which later can be recycled into a new ink for the next round of 3D printing. In the first printing cycle, a high-viscous ink is first slightly cured and is then printed at an elevated temperature into complicated 3D structures, followed by an oven cure using a two-step approach. To be recycled, the printed epoxy parts are fully dissolved in an ethylene glycol solvent in a sealed container at a high temperature. The dissolved polymer solution is reused for the next printing cycle using similar printing conditions. Our experiments demonstrate that the ink can be printed four times and still retains very good printability. In addition, the vitrimer epoxy can be used for pressure-free repairs for the 3D printed parts.

Graphical abstract: Recyclable 3D printing of vitrimer epoxy

Supplementary files

Article information

Article type
Communication
Submitted
22 Jan 2017
Accepted
05 Eph 2017
First published
05 Eph 2017

Mater. Horiz., 2017,4, 598-607

Recyclable 3D printing of vitrimer epoxy

Q. Shi, K. Yu, X. Kuang, X. Mu, C. K. Dunn, M. L. Dunn, T. Wang and H. Jerry Qi, Mater. Horiz., 2017, 4, 598 DOI: 10.1039/C7MH00043J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements