Issue 21, 2017

Hierarchical structure and porosity in UiO-66 polyMOFs

Abstract

The first polymer–MOF hybrid material (polyMOF) with a UiO-66 architecture is reported, prepared from polymers with varying alkyl spacers, molecular weights, and dispersities. With appropriate spacing, mesoporous UiO-66 polyMOF can be obtained having an uncommon, interlaced crystal morphology, suggesting that polyMOFs can be used to generate MOF materials with hierarchical architectures.

Graphical abstract: Hierarchical structure and porosity in UiO-66 polyMOFs

Supplementary files

Article information

Article type
Communication
Submitted
24 Dis 2016
Accepted
21 Feb 2017
First published
21 Feb 2017

Chem. Commun., 2017,53, 3058-3061

Hierarchical structure and porosity in UiO-66 polyMOFs

S. Ayala, Z. Zhang and S. M. Cohen, Chem. Commun., 2017, 53, 3058 DOI: 10.1039/C6CC10225E

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