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The addition of a small amount of sulfonated multi-walled carbon nanotubes (3 wt%) to a sulfonated polyarylene ether nitriles (SPEN) proton exchange membrane using an acyl chloride method was proved to be an effective way to improve the mechanical behaviour and proton conductivity performance.

Graphical abstract: Sulfonated carbon nanotubes synergistically enhanced the proton conductivity of sulfonated polyarylene ether nitriles

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