Issue 19, 2015

Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

Abstract

Reactions of the dianion [Te(tBuN)P(μ-NtBu)2P(NtBu)Te]2− with I2 or [Cp*RhCl2]2 unexpectedly produced complexes of the novel spirocyclic Te5 dianion [{tBuN(Te)P(μ-NtBu)2P(Te)NtBu}2μ-Te]2−, which is N,N′-coordinated to two Na+ ions in the disodium derivative and adopts a Te,Te′,Te′′-bonding mode in the Cp*Rh complex.

Graphical abstract: Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

Supplementary files

Article information

Article type
Communication
Submitted
21 Okt 2014
Accepted
03 Dis 2014
First published
06 Jan 2015

Dalton Trans., 2015,44, 8781-8783

Sodium and rhodium complexes of a spirocyclic Te5 dianion supported by P2N2 rings

A. Nordheider, K. S. Athukorala Arachchige, A. M. Z. Slawin, J. D. Woollins and T. Chivers, Dalton Trans., 2015, 44, 8781 DOI: 10.1039/C4DT03257H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements