Spin polarization in electrodeposited thin films of the molecule-based magnetic semiconductor Cr5.5(CN)12·11.5H2O

Eugenio Coronado; Juan P. Prieto-Ruiz; Helena Prima-Garcia

doi:10.1039/C3CC45036H

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Spin polarization in electrodeposited thin films of the molecule-based magnetic semiconductor Cr_5.5(CN)₁₂·11.5H₂O†

Eugenio Coronado,*^a Juan P. Prieto-Ruiz^a and Helena Prima-Garcia*^a

Author affiliations

* Corresponding authors

^a Instituto de Ciencia Molecular (ICMol), Universitat de València, C/Catedrático José Beltrán, 2, 46980-Paterna, Spain
E-mail: helena.prima@uv.es, eugenio.coronado@uv.es

Abstract

The magnetoresistance (MR) effect of thin films of the Prussian Blue Analogue (PBA) Cr_5.5(CN)₁₂·11.5H₂O, prepared by electrochemical deposition, has been measured using the standard two-point probe method. This molecule-based ferrimagnetic material, with a T_c = 240 K, exhibits MR up to 2% at 6 T and 200 K.

This article is part of the themed collection: Molecular Spintronics

Download options Please wait...

Supplementary files

Supplementary information PDF (1305K)

Article information

DOI: https://doi.org/10.1039/C3CC45036H
Article type: Communication
Submitted: 04 Jul 2013
Accepted: 27 Aga 2013
First published: 03 Sep 2013

Download Citation

Chem. Commun., 2013,49, 10145-10147

Permissions

Request permissions

Spin polarization in electrodeposited thin films of the molecule-based magnetic semiconductor Cr_5.5(CN)₁₂·11.5H₂O

E. Coronado, J. P. Prieto-Ruiz and H. Prima-Garcia, Chem. Commun., 2013, 49, 10145 DOI: 10.1039/C3CC45036H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications