From changes in the e.s.r. spectrum for Me2ĊC(Br)Me2 radicals, it is deduced that the stable structure is asymmetric, but that the rate of migration of bromine between the two equivalent sites becomes fast on the e.s.r. time-scale at ca 100 K.
S. P. Maj, M. C. R. Symons and P. M. R. Trousson, J. Chem. Soc., Chem. Commun., 1984, 561 DOI: 10.1039/C39840000561
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