Issue 75, 2018
From the journal:

Chemical Communications

Phosphine free Mn-complex catalysed dehydrogenative C–C and C–heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives†

Kalicharan Das, ORCID logo a   Avijit Mondala  and  Dipankar Srimani ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology-Guwahati, Kamrup, Assam 781039, India
E-mail: dsrimani@iitg.ernet.in

Abstract

Herein the first sustainable synthesis of quinoxalines, pyrazines and benzothiazoles catalysed by a phosphine free Mn(I) complex via acceptorless dehydrogenative coupling (ADC) is reported. This method is also applied successfully to synthesize quinolines via the dehydrogenation (removal of H2) and condensation (removal of H2O) reaction between 2-aminobenzyl alcohols and secondary alcohols.

Graphical abstract: Phosphine free Mn-complex catalysed dehydrogenative C–C and C–heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives

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Article information

DOI
https://doi.org/10.1039/C8CC05877F
Article type
Communication
Submitted
19 Jul 2018
Accepted
23 Aga 2018
First published
24 Aga 2018

Chem. Commun., 2018,54, 10582-10585

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Phosphine free Mn-complex catalysed dehydrogenative C–C and C–heteroatom bond formation: a sustainable approach to synthesize quinoxaline, pyrazine, benzothiazole and quinoline derivatives

K. Das, A. Mondal and D. Srimani, Chem. Commun., 2018, 54, 10582 DOI: 10.1039/C8CC05877F

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