Issue 35, 2018

Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

Abstract

We report the design and synthesis of two Co2+ and Zn2+ phthalocyanine (PC)-based redox active metal–organic conjugated microporous polymers (MO-CMP), CoCMP and ZnCMP, respectively, obtained by a Schiff base condensation reaction. CoCMP, where Co2+ is stabilized by N4-coordination of PC, has shown stable and efficient electrocatalytic activity towards the OER with a low overpotential of 340 mV.

Graphical abstract: Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

Supplementary files

Article information

Article type
Communication
Submitted
13 Feb 2018
Accepted
27 Mas 2018
First published
29 Mas 2018

Chem. Commun., 2018,54, 4465-4468

Metallophthalocyanine-based redox active metal–organic conjugated microporous polymers for OER catalysis

A. Singh, S. Roy, C. Das, D. Samanta and T. K. Maji, Chem. Commun., 2018, 54, 4465 DOI: 10.1039/C8CC01291A

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