Issue 26, 2016

A band-gap-graded CZTSSe solar cell with 12.3% efficiency

Abstract

Although Cu2ZnSn(S,Se)4 (CZTSSe) has attracted attention as an alternative to CuInGaSe2 (CIGS) as an absorber material in solar cells, its low efficiency is a serious shortcoming preventing its commercialization. To realize a high-efficiency CZTSSe solar cell, improved grain crystallinity, inhibited secondary-phase formation, controlled defect generation, adequate Na content, and band gap grading are required in the absorber layer. Few studies have focused specifically on band gap grading. In this study, a method of using SeS2, a new potential chalcogenization source material, to control the S and Se contents in a CZTSSe absorber and its effects were investigated. Using an appropriate SeS2/Se weight ratio, band gap grading was realized within the depletion region. By increasing the value of VOC through band gap grading in the depletion region, a record VOC deficit of 0.576 V was achieved. Furthermore, the possibility of enhancing JSC through the formation of a type-inverted n-type phase at the absorber surface in response to an appropriate alignment of the conduction-band minimum energy level and the Fermi energy pinning level is discussed. By introducing the chalcogenization source material SeS2 during the annealing process, CZTSSe solar cells with a maximum efficiency of 12.3% were obtained.

Graphical abstract: A band-gap-graded CZTSSe solar cell with 12.3% efficiency

Supplementary files

Article information

Article type
Paper
Submitted
22 Feb 2016
Accepted
27 Eph 2016
First published
27 Eph 2016

J. Mater. Chem. A, 2016,4, 10151-10158

A band-gap-graded CZTSSe solar cell with 12.3% efficiency

K. Yang, D. Son, S. Sung, J. Sim, Y. Kim, S. Park, D. Jeon, J. Kim, D. Hwang, C. Jeon, D. Nam, H. Cheong, J. Kang and D. Kim, J. Mater. Chem. A, 2016, 4, 10151 DOI: 10.1039/C6TA01558A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements