Accessing chiral sulfones with an all-carbon quaternary stereocenter via photoinduced asymmetric Truce–Smiles rearrangement and radical sulfur dioxide insertion

Chenxin Wang, Wei Xiao and Jie Wu

Org. Chem. Front., 2025, 12, 4469
DOI: 10.1039/D5QO00383K

Photoredox-catalyzed cascade difluoromethylation/SO2 reintegration/polyfluoroarylation of conjugated dienes with a bifunctional CF2HSO2Na reagent

Kehan Jiao, Yunliang Guo, Jiuli Xia, Kaixuan Chen, Lihan Zhu, Ying Dong, Jiao Qu, Guangfan Zheng, Jiaqiong Sun, Tao Xiong and Qian Zhang

Green Chem., 2026, 28, 3215
DOI: 10.1039/D5GC05765E

Access to ester-substituted γ-butyrolactones via photocatalyzed alkoxycarbonylation/lactonization of alkenoic acids

Yuping Xiong, Ping Liang, Wenlin Xie, Jian-Qiang Chen and Jie Wu

Org. Chem. Front., 2025, 12, 5039
DOI: 10.1039/D5QO00520E

Radical-mediated sulfonylation relay of alkyl alkynes/alkenes and electron-deficient alkenes to access vinyl and alkyl sulfones

Jin-Hui Liu, Fang Long, Qing Li, Da-Zhi Sun, Ying Man, Lin Wang, Li-Jun Wu and Shuang-Feng Yin

Org. Chem. Front., 2025, 12, 3299
DOI: 10.1039/D5QO00214A

Deep eutectic solvents as sustainable media for multicomponent sulfonylation: an efficient strategy to synthesize (hetero)aryl sulfones

Haibo Zhu, Yangbo Zhong, Liyuan Yan, Honglei Zhang, Yajing Shen, Zhanggao Le, Qiangwen Fan and Zongbo Xie

Green Chem., 2024, 26, 1387
DOI: 10.1039/D3GC04395A

Visible-light-induced 1,3-difunctionalization of allylboronic esters enabled by a 1,2-boron shift

Panjie Xiang, Kai Sun, Anzai Shi, Jiangzhen An, Xiaolan Chen, Lingbo Qu and Bing Yu

Green Chem., 2025, 27, 1820
DOI: 10.1039/D4GC06330A

A general photocatalytic strategy for the synthesis of β-hydroxy acid derivatives from alkenes

Meiling Chen, Jingjing Yang, Wei Xiao, Jian-Qiang Chen and Jie Wu

Org. Chem. Front., 2025, 12, 516
DOI: 10.1039/D4QO01685H

Chemodivergent dearomatization of benzene-linked O-oxime esters via EnT-induced radical cross-coupling

Guohui Zeng, Dongwen Guo, Huanfeng Jiang and Biaolin Yin

Chem. Sci., 2025, 16, 2690
DOI: 10.1039/D4SC07681H

Radical sulfonylation with sulfur dioxide surrogates

Wei Xiao, Jian-Qiang Chen and Jie Wu

Chem. Soc. Rev., 2025, 54, 6832
DOI: 10.1039/D4CS01312C

Photoinduced EnT-mediated sulfonamidylimination of alkenes and (hetero)arenes with iminophenylacetic acid oxime esters

Zetian Sun, Jianting Zhang, Xiaohua Du, Lulu Liu, Shuo Gao, Chenchen Qi, Xiaoqing Li and Xiangsheng Xu

Chem. Commun., 2024, 60, 7934
DOI: 10.1039/D4CC02225D

Access to chiral β-amino sulfones from acrylamides and sulfur dioxide by iron catalysis

Liping Luo, Xuemei Zhang, Chunxi Huang and Zhong Lian

Org. Chem. Front., 2024, 11, 1678
DOI: 10.1039/D3QO02004E

Photoredox-catalyzed three-component radical coupling of potassium alkyltrifluoroborates, DABSO and polyfluoroarenes

Yunliang Guo, Jiuli Xia, Kaixuan Chen, Kehan Jiao, Ying Dong, Guangfan Zheng, Jiao Qu, Jiaqiong Sun, Tao Xiong and Qian Zhang

Org. Chem. Front., 2026, 13, 202
DOI: 10.1039/D5QO01163A

Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones

Qinqiong Zeng, Yujia Gong, Xiaochun He, Xuemei Zhang and Zhong Lian

Org. Chem. Front., 2024, 11, 6340
DOI: 10.1039/D4QO01376J

Synthesis of 3,3-dialkyl-substituted isochroman-1,4-diones via copper/photoredox dual-catalyzed carbolactonization of alkenes

Pengfei Zhou, Ziyu Jin, Qiuping Ding, Jian-Qiang Chen and Jie Wu

Org. Chem. Front., 2025, 12, 7019
DOI: 10.1039/D5QO01082A

Synthesis of benzo[f][1,2]thiazepine 1,1-dioxides based on the visible-light-mediated aza Paternò–Büchi reaction of benzo[d]isothiazole 1,1-dioxides with alkenes

Yi-Lin Wang, Peng-Xiang Liu, Huan-Huan Zhang, Peng-Fei Xu and Yong-Chun Luo

Chem. Commun., 2023, 59, 12467
DOI: 10.1039/D3CC03745B

Visible-Light-Mediated Sulfonylation of Arenes via Catalytic Electron Donor–Acceptor Complex of Thianthrenium Salts

Liangke Guo, Jiangzhen An, Haoran Liu, Bailing Zhou, Kai Sun, Fuyi Zhang, Xiaolan Chen, Peng Liu, Lingbo Qu and Bing Yu

ACS Sustainable Chem. Eng., 2025, 13, 14939
DOI: 10.1021/acssuschemeng.5c05040

Three-Component Photochemical 1,2,5-Trifunctionalizations of Alkenes toward Densely Functionalized Lynchpins

Fritz Paulus, Colin Stein, Corinna Heusel, Tobias J. Stoffels, Constantin G. Daniliuc and Frank Glorius

J. Am. Chem. Soc., 2023, 145, 23814
DOI: 10.1021/jacs.3c08898

Lanthanoids in Hydroarylaminations: Yb(III)- and Tb(III)-Catalyzed Addition of Arylamines to Activated Olefins

Rajagopal Rajesh, Olencheri Karimpanakkal Sandhya, Sunilkumar Puthenpurackal Narayanan and Rajesh Kunjanpillai

Synthesis, 2024, 56, 2047
DOI: 10.1055/a-2282-7702

Copper-Catalyzed Vicinal Thiocyanosulfonylation of Alkenes and Alkynes

Meng-Fan Duan, Mei Xiao, Olukayode Olamiji Ogundipe, Xin-Xin Wu and Jian-Ping Zou

J. Org. Chem., 2024, 89, 11558
DOI: 10.1021/acs.joc.4c01241

Alcohol Activation by Benzodithiolylium for Deoxygenative Alkylation Driven by Photocatalytic Energy Transfer

Bin‐Qing He, Lu Zhao, Jun Zhang, Wen‐Hui Bao, Mingjun Yang and Xuesong Wu

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202423795

Aminosulfonylation of Alkenes for the Synthesis of β-Amino Sulfone Derivatives

Hengyue Zhang, Xingda Zhao, Ruihan Yan and Weilong Lin

Org. Lett., 2024, 26, 4251
DOI: 10.1021/acs.orglett.4c01103

Photocatalytic Cascade Reaction of Allylamines for the Synthesis of Ester-Containing Imidazolines and Oxazolidines

Zhipeng Zong, Jian-Qiang Chen and Jie Wu

Org. Lett., 2025, 27, 12795
DOI: 10.1021/acs.orglett.5c04090

Radical-Induced Decarboxylation/Cyclization of Benzoyl Peroxides with 1,8-Enynes through In Situ SO2 Insertion/Smiles Rearrangement Relay Strategy

Long-Jin Zhong, Si-Wei Tian, Peng-Fei Huang, Jian-Hong Fan, Quan Zhou and Yu Liu

J. Org. Chem., 2026, 91, 3262
DOI: 10.1021/acs.joc.5c03044

Visible light-mediated dearomative spirocyclization/imination of nonactivated arenes through energy transfer catalysis

Chao Zhou, Elena V. Stepanova, Andrey Shatskiy, Markus D. Kärkäs and Peter Dinér

Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-58808-0

Thioxanthone: A Benchmark Photocatalyst for Organic Synthesis

Vera P. Demertzidou, Elpida Skolia and Christoforos G. Kokotos

ChemCatChem, 2025, 17
DOI: 10.1002/cctc.202500760

Alkyl Radical Initiated Cyclization/Cascade for Synthesizing Lactam‐Substituted Alkyl Sulfones

Li‐Jun Wu, Kai‐Yi Zhang, Pei Yang, Chuan‐Chong Peng, Jin‐Hui Liu, Qing Li, Da‐Zhi Sun and Shuangfeng Yin

Chin. J. Chem., 2024, 42, 1853
DOI: 10.1002/cjoc.202400154

Conversion of Carboxylic Acids to Sulfonamide Bioisosteres via Energy Transfer Photocatalysis

Zhipeng Zong, Jingjing Yang, Lulu Yuan, Xiaojie Wang, Jian-Qiang Chen and Jie Wu

Org. Lett., 2024, 26, 8626
DOI: 10.1021/acs.orglett.4c03325

Recent Advances in Nickel-Catalyzed Ring Opening Cross-Coupling of Aziridines

Jianqiang Chen, Gangguo Zhu and Jie Wu

Acta Chimica Sinica, 2024, 82, 190
DOI: 10.6023/A23110503

Alcohol Activation by Benzodithiolylium for Deoxygenative Alkylation Driven by Photocatalytic Energy Transfer

Bin‐Qing He, Lu Zhao, Jun Zhang, Wen‐Hui Bao, Mingjun Yang and Xuesong Wu

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202423795

closo‐Carboranylanaloga von β‐Arylethylaminen: Direkte Synthese aus Alkenen mittels EnT‐Katalyse

Fritz Paulus, Corinna Heusel, Marc Jaspers, Lilli M. Amrehn, Florian Schreiner, Debanjan Rana, Constantin G. Daniliuc, Michael Ryan Hansen and Frank Glorius

Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202504793

Research Progress on Visible-Light-Induced Energy Transfer Strategy for the Difunctionalization of Alkenes via Oxime Esters

晴雨万

JOCR, 2026, 14, 86
DOI: 10.12677/jocr.2026.141008

Visible-Light-Induced Energy-Transfer-Mediated Hydrofunctionalization and Difunctionalization of Unsaturated Compounds via Sigma-Bond Homolysis of Energy-Transfer Acceptors

Qiao Sun, Shao-Peng Wang, Yuan Xu, Aihua Yin, Liu Yang, Jingheng Zhu, Chun-Ling Zheng, Guowei Wang, Zheng Fang, Shanhong Sui, Daixi Wang, Yan Dong, Dongshun Zhang, Chang-Sheng Wang and Kai Guo

ACS Catal., 2025, 15, 1854
DOI: 10.1021/acscatal.4c07316

Recent Advances in Radical-Based Dehydroxylation of Hydroxyl Groups via Oxalates

Jianqiang Chen, Gangguo Zhu and Jie Wu

Acta Chimica Sinica, 2023, 81, 1609
DOI: 10.6023/A23070339

Photoredox-catalyzed synthesis of α,α-difluoromethyl-β-alkoxysulfones from sulfur dioxide

Minjun Yin, Yuhui Lin, Manli Zhuang, Wei Xiao and Jie Wu

Chinese Chemical Letters, 2025, 36, 109926
DOI: 10.1016/j.cclet.2024.109926

Photoinduced Aminosulfonylation of Unactivated Alkenes via N–N Bond Cleavage and Distal Migration of Imine

Xin Liu, Longyu Wang, Muliang Zhang and Shi-Kai Tian

Org. Lett., 2025, 27, 6743
DOI: 10.1021/acs.orglett.5c01861

Formal α-Nucleophilic Addition to Electron-Deficient Alkenes by Photoredox and Copper Dual Catalysis

Yuping Xiong, Zhiyi Zhou, Yahan Zhang, Jian-Qiang Chen and Jie Wu

Org. Lett., 2025, 27, 8915
DOI: 10.1021/acs.orglett.5c02573

Functionalization of Cubane Formation of C−C and C−Heteroatom Bonds

Tomohiro Yasukawa, Katja S. Håheim and Janine Cossy

Helvetica Chimica Acta, 2024, 107
DOI: 10.1002/hlca.202300200

closo‐Carboranyl Analogs of β‐Arylethylamines: Direct Synthesis from Alkenes via EnT‐Catalysis

Fritz Paulus, Corinna Heusel, Marc Jaspers, Lilli M. Amrehn, Florian Schreiner, Debanjan Rana, Constantin G. Daniliuc, Michael Ryan Hansen and Frank Glorius

Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202504793

Photosensitized Imino-Sulfamoylation of Alkenes with Oxime Carbamates

Ai-Lian Wang, Huan-Huan Zhao, Hao-Wen Jiang and Peng-Fei Xu

Org. Lett., 2025, 27, 4880
DOI: 10.1021/acs.orglett.5c01128

Photochemical Generation of Sulfide Radical Cations and Their Synthetic Applications

Yuping Xiong, Wenlin Xie, Jianqiang Chen and Jie Wu

Acta Chimica Sinica, 2025, 83, 1592
DOI: 10.6023/A25090302