Unlocking sunlight driven photocatalysis: synthesis, diversity, and applications of COF-based S-scheme heterojunctions

Irshad Ahamd, Zaheer Ud Din Babar, Yifei Zhang, Ayman Al-Qattan, Samia Ben Ahmed and Gao Li

J. Mater. Chem. A, 2025, 13, 15517
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Recent advances in interface engineering of bismuth-based materials for photocatalytic CO2 reduction

Swetha S. M. Bhat and Girish Kumar S.

RSC Appl. Interfaces, 2025, 2, 1507
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Potential application of bismuth oxyiodide (BiOI) when it meets light

Zaichun Sun and Tahta Amrillah

Nanoscale, 2024, 16, 5079
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Scaling up the charge transfer on Pd@Ti3C2Tx–TiO2 catalysts: a sustainable approach for H2 generation via water splitting

Muhammad Zeeshan Abid, Khezina Rafiq, Abdul Rauf, Raed H. Althomali and Ejaz Hussain

Mater. Adv., 2024, 5, 2238
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A bioinspired floatable system with a 3D sandwich-type triphase interface for highly efficient nitrogen fixation

Xiuyan Wang, Xinjian Shi, Shengyan Yin, Ping She, Jiaqi Zheng, Yudong Song and Hang Sun

J. Mater. Chem. A, 2023, 11, 9976
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Experimental and theoretical investigation on facet-dependent MoO2/BiOBr Z-scheme heterojunction photocatalytic nitrogen reduction: modulation of bulk charge separation efficiency by built-in electric field intensity

Zhuying Chen, Zhiling Huang, Jieyi Yang, Yue Meng, Bo Xie, Zheming Ni and Shengjie Xia

J. Mater. Chem. A, 2024, 12, 16877
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Effect of fuel dosage in self-propagation combustion: evolution of BiOCl to BiOCl/Bi24O31Cl10 heterojunctions enriched with oxygen vacancies

Han Liu, Wenjun Zhang and Meng Chen

New J. Chem., 2024, 48, 15379
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Scaling up clean production of biomass-derived organic acids as a step towards the realization of dual carbon goals: a review

Zulfiqar Ali, Jiliang Ma and Runcang Sun

Green Chem., 2024, 26, 11061
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Optimizing CO2 photoreduction on bismuth oxyhalides via intrinsic and extrinsic techniques

Malik Zeeshan Shahid, Zhihao Chen, Rashid Mehmood, Meng Zhang, Danrui Pan, Shishun Xu, Umar Farooq, Ahmed Mahmoud Idris and Zhengquan Li

J. Mater. Chem. A, 2024, 12, 1392
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Hydrogen defects in LaBi2O4X (X = Cl, Br, and I) Sillén oxyhalide phases and their impacts on ionic transport

ShinYoung Kang, Andrew J. E. Rowberg, Shenli Zhang and Joel B. Varley

J. Mater. Chem. A, 2026
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Novel S-scheme g-C3N4/OVs-BiOCl heterostructure nanosheets for photocatalytic degradation of tetracycline

Xiaoyan Lian, Ting Cai, Jiawei Wu, Feng Zhang and Kangzhen Xu

Journal of the Taiwan Institute of Chemical Engineers, 2026, 178, 106374
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Bi2O2CO3-coating on beverage-derived carbon microspheres to achieve highly-efficient photocatalysts for ciprofloxacin degradation

Xinxue Qiu, Xiaofeng Sun, Jinyuan Ma, Zao Yi, Guorong Liu, Jianfeng Dai and Hua Yang

Journal of Alloys and Compounds, 2024, 970, 172608
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Synergistic efficiency of functionalized MWCNT stimulated ZnFe2O4/BiOBr heterostructure for enhanced removal of brilliant green and tetracycline hydrochloride

Iftekhar Ahmad, Mohammad Saud Athar, Ziyaur Rasool and Mohammad Muneer

Journal of Industrial and Engineering Chemistry, 2025, 141, 203
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The new role of BiOCl photocatalyst in piezophotocatalysis mimicking natural conditions: The role of crystal structure in the piezoelectric effect

Patrycja Wilczewska, Natalia Górecka, Karol Szczodrowski, Beata Kalska-Szostko, Jacek Ryl and Ewa Maria Siedlecka

Journal of Environmental Chemical Engineering, 2025, 13, 115921
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BiOX-loaded biohybrid magnetic microrobots for enhanced photocatalysis under visible light

De Gong, Yan Li, Hui Zhou, Bo Gu, Nuoer Celi, Deyuan Zhang and Jun Cai

Applied Materials Today, 2023, 35, 101915
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Oxygen vacancy and boron dual sites enable efficient oxygen activation for emerging contaminant degradation: Boosted exciton dissociation via built-in electric field modulation

Guanglan Di, Ruyu Shu, Dajun Han, Jiaowei Ding, Zefang Chen, Xuede Li, Xiangwei Wu and Xiaoli Zhao

Applied Catalysis B: Environment and Energy, 2025, 362, 124754
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Hierarchical S-scheme heterojunctions of ZnIn2S4-decorated TiO2 for enhancing photocatalytic H2 evolution

Baolong Zhang, Fangxuan Liu, Bin Sun, Tingting Gao and Guowei Zhou

Chinese Journal of Catalysis, 2024, 59, 334
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Zinc-doped BiOBr microspheres as an efficient photocatalyst for tetracycline antibiotic degradation under LED light

Tien Van Huynh, Sang Thanh Nguyen, Vinh Huu Nguyen and Oanh T.K. Nguyen

Journal of Physics and Chemistry of Solids, 2026, 214, 113669
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Visible light response SnFe2O4/BiOCl microspheres: Sysnthesis, magnetical and photocatalytic properties

Gehong Zhang, Zongliang Hou, Pingge Zhao, Mengnan Chao, Zhuopu Li, Xu Zhao, Yanjun Lu and Xian Zhang

Journal of Alloys and Compounds, 2024, 1008, 176732
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TiO2-Coated BiOCl Nanosheet p-n Heterojunctions for Photocatalytic H2O2 Production under Simulated Sunlight

Mingming Du, Anxian Peng, Hongyue Liu, Huimei Chen, Qiyun Li, Zheng Fang, Ganning Zeng and Rongjun Yan

ACS Appl. Nano Mater., 2025, 8, 12222
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Constructing BiOF@PCN − 222 MOF heterojunction to remove tetracycline under visible light rapidly and efficiently

Yu Zhang, Xungu Cao, Yuchang Liu, Yunkun Zhao and Xiaohong Hou

Journal of Water Process Engineering, 2024, 67, 106184
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Economic Photocatalytic Degradation of Environmental Pollutants Over CuBi2O4/Ag2CrO4 Photocatalyst with Core-Shell Heterostructure: S-Scheme Mechanism

Zaid H. Jabbar, Bassim H. Graimed, Ayah A. Okab, Huda S. Merdas, Ahmed Makki Al-Sulaiman and Ali Majdi

J Clust Sci, 2025, 36
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A flower-like metal-organic frameworks fabricated BiOCl heterojunction with enhanced visible light photocatalytic activity

Yuhong Wang, Dongsheng Wang, Hu Xu, Jun Yu and Tingting Chen

Journal of Alloys and Compounds, 2023, 957, 170376
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Unveiling cutting-edge progress in the fundamentals of MXene: Synthesis strategies, energy and bio-environmental applications

Ikhtiar Gul, Murtaza Sayed, Tooba Saeed, Faiza Rehman, Abdul Naeem, Saman Gul, Qaiser Khan, Kausar Naz and Mushtaq ur Rehman

Coordination Chemistry Reviews, 2024, 511, 215870
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Lattice distortion and electronic structure dual engineering of Bi4O5Br2 nanosheets for enhanced photocatalytic activity

Huayang Tian, Yihan Song, Ruoyang Zhang, Qi Wang, Yujie Ning and Bin Liu

Chemical Engineering Journal, 2025, 508, 161000
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One-pot cascade process for efficient upgrading of furfural to γ-valerolactone over adjustable Lewis-Brønsted bi-acidic catalyst

Jiarong Qiu, Yi Liu, Jingwen Zhang, Ben Zhou, Qiyue Yang, Liangqing Zhang, Jianfeng Chen, Bingshu Wang, Lu Lin and Xianhai Zeng

Industrial Crops and Products, 2024, 214, 118474
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Erythritol assisted facile green synthesis of bismuth-rich photocatalyst Bi7O9I3 with enhanced photocatalytic degradation performance

Qi-Hui Liu, Hui-Long Wang, Hao Huang and Wen-Feng Jiang

Journal of Environmental Chemical Engineering, 2023, 11, 110611
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Bismuth-based Catalysts for Efficient Photocatalytic CO2 Reduction Reaction: A Mini-review

Jianzhi Wang, Qingyi Lu, Zhenggui Wei, Jun Cheng and Zhi-Gang Gao

Korean J. Chem. Eng., 2026, 43, 1355
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Designed composite catalysts of Cu-doped BiOCl nanosheets on CuFe-PBA cubes for enhanced photoelectrochemical H2 evolution activity in neutral medium

Dianhua Song, Yaxin Liu, Caixia Sun, Yan Zhao, Ting Zhu, Ruijie Yang, Yuehong Song and Jingzhe Zhao

Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2023, 679, 132592
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Sparking a comparative study between selective Bi-based photocatalysts (BiOCl, Bi12O17Cl2, and CuBi2O4) depending on their photocatalytic characteristics and degradation activity

Zaid H. Jabbar, Bassim H. Graimed, Hayder M. Rashid, Saad H. Ammar, Maye M. Alsunbuli and Ayah A. Okab

J Nanopart Res, 2025, 27
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One-step construction of BiOBr@H3PW12O40@BiOI heterostructure: Conducting photogenerated electrons through W 5d electron bridge for enhancing the photocatalytic activity

Rui Sun, Hongtao Li, Yudan Zhang, Junyi Hua, Wenxin Xu, Kexin Li, Huiqin Guo, Liushui Yan and Shenglian Luo

Molecular Catalysis, 2024, 555, 113845
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Piezoelectric catalysts for water pollutant remediation: Achievements, challenges, and perspectives

Yuchuan Lu, Chenglin Hao, Sanshuang Gao, Xue Zhao, Xuguang An and Guangzhi Hu

Materials Today, 2025, 88, 415
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Innovative ternary composite photocatalyst: BiOCl/Bi12O17Cl2/Bi2O3 for sustainable water remediation

Helena Pérez del Pulgar, Josefa Ortiz-Bustos, Almudena Torres-Pardo, Marina Parras, Isabel del Hierro and Yolanda Pérez

Applied Surface Science, 2024, 660, 160028
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Building a robust S-scheme BiOCl/CuBi2O4 system for photocatalytic oxidation of sulfamethoxazole under solar light irradiation

Zaid H. Jabbar, Ayah A. Okab, Bassim H. Graimed, Saad H. Ammar, Haidar Taofeeq and Mortatha Al-Yasiri

Solar Energy, 2024, 275, 112640
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Immobilization-Free Photoelectrochemical Aptasensor for Atrazine Based on Bifunctional Graphene Signal Amplification and a Controllable Sulfhydryl-Assembled BiOBr/Ag NP Microinterface

Huanhuan Sun, Ye Feng, Ziwei Zhang, Bingyu Du, Guangqiu Lu and Meichuan Liu

Anal. Chem., 2023, 95, 15736
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Investigation on thermodynamic stability and electronic structure properties of Bi2CrO6 (0 0 1) surface using density functional theory

Yao Zhu, Anqi Yang, Shengshang Lu, Yilong Tian, Quan Xie and Qingquan Xiao

Computational Materials Science, 2024, 244, 113168
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Anchoring modified g-C3N4 with Bi5O7Br: S-scheme photocatalysts with boosted activities in elimination of inorganic and organic pollutants

Zahra Jalalat, Aziz Habibi-Yangjeh, Paria Hemmati-Eslamlu and Yuksel Akinay

Inorganic Chemistry Communications, 2023, 158, 111565
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Functionalizing magnesium slag in alkali-activated cementitious material for high-efficiency degradation of formaldehyde

Yidi Wang, Yu Wang, Na Zhang, Xiaojun Zhang, Jiale Zhang, Ping Lu, Shouhang Cui and Yihe Zhang

Construction and Building Materials, 2025, 484, 141758
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Clean production of lactic acid by selective carbon-carbon bond cleavage of biomass feedstock over a novel carbon-bismuth oxychloride photocatalyst

Zulfiqar Ali, Jiliang Ma, Dongnv Jin, Rui Cui and Runcang Sun

Front. Chem. Sci. Eng., 2024, 18
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In situ co-crystallization synthesis of the direct Z-scheme Bi5O7I/Bi2SiO5 heterojunction for enhanced photocatalytic rhodamine B and ciprofloxacin degradation

Mingliang Zhang, Fangfang Duo, Chubei Wang, Jianwei Zhou, Liangliang Chu, Jihong Lan, Junwei Li and Lixiang Li

Inorganic Chemistry Communications, 2024, 159, 111729
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Highly Efficient Rutile TiO2 Endowed by Electron-Capturing Center and Plasma Effect for Enhanced Solar Water Splitting

Xin Tao, Yihai Zhou, Meng Pan, Shenghui Liu, Yong Zhou and Renchun Yang

ACS Catal., 2025, 15, 1242
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Construction and synthesis of S-WO₃/BiInOCl photocatalyst via synergistic ion doping and heterojunction engineering for efficient degradation of MB

Chenxi Cui, Lingxiu Shu, Changchun Chen, Xia Xu, Zhixiong Huang, Zisheng Guan, Yifeng Wang and Lin Pan

FlatChem, 2025, 52, 100901
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Bismuth nanostructures: catalytic pathways to sustainable technologies

Muhammad Khan, Mohamed Hassan Eisa, Xiaohui Sun, Muffarih Shah, Suleiman M. Suleiman, Abdul Hameed, Ilyas Khan, Xiangsheng Chen, Nasir A. Ibrahim, Ashraf A. Qurtam, Zainuriah Hassan, Katabathini Narasimharao and Asmiet Ramizy

Fuel, 2026, 415, 138228
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Designing Highly Efficient Z-Scheme BiOCl/BiOI Heterojunctions and Oxygen Vacancy-Rich BiO(Cl,I) Solid Solutions for Visible-Light-Driven Mineralization of Aqueous Pollutants

Meiting Li, Bingxin Yuan, Chi Zhang, Jia Li and Xuejiao Wang

Langmuir, 2025, 41, 14397
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Fe reaction sites enhance the removal of tetracycline over Fe-Bi3O4Br with intensified adsorption and photocatalysis

Wenhai Zhang, Zhaoyong Bian, Feng Wang and Qiang Zhang

Separation and Purification Technology, 2025, 356, 129893
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An electrostatic self-assembled Z-scheme heterojunction photocatalyst achieving breakthrough performance in organic pollutants decomposition and hydrogen production

Panpan Jing, Chaoyue Zhao, Peifeng Wang and Nan Guo

Materials Today Nano, 2026, 33, 100757
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Sustainable innovative technologies for a circular economy: Artificial photosynthesis, photobiorefineries, bioplastics, waste-to-wealth, and thermoelectric generators

Ganeshraja Ayyakannu Sundaram, Rajkumar Kanniah, Mani Sivakumar and Jenif D'souza Antonisamy

Biomass and Bioenergy, 2025, 202, 108219
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Fe-O-Bi efficient electron transfer channels and photo-Fenton synergy in S-scheme heterojunctions: Insights into interfacial interactions and ofloxacin degradation

Jiawei Liu, Jun Shi and Huiping Deng

Green Energy & Environment, 2025, 10, 1503
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Intrinsic high-temperature ferroelectricity, superferroelasticity, and deep-ultraviolet nonlinear optical response of GaOCl monolayer

Zhengyuan Tu, Yunhua Wang, Weitu Liao, Tao Hu and Shengjun Yuan

Phys. Rev. Materials, 2024, 8
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Fabrication of Eu-doped 3D flower-like BiOBr photocatalyst for boosted photoreduction CO2 performance

Tao Ding, Yiran Hu, Zhen Nie, Qian Wu, Mianping Zheng and Yong Huang

Chemical Physics Letters, 2025, 859, 141774
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Manganese-based metal-organic framework preferentially photocatalytically degraded high electronegativity groups in methyl orange

Huijun Chen, Jierou Lin and Shixiong Li

Journal of Solid State Chemistry, 2025, 351, 125546
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Uniform dispersion of Bi2Sn2O7 nanoparticles on intersectional CuO monolayers for levofloxacin photodegradation: Exploring influence of morphology on S-type charge migration

Davood Fayazi, Armin Dolatimehr, Ali Teymoori, Sepideh Khalili, Nima Mahmoudzadeh Vaziri and Zahra Khaksar

Journal of Water Process Engineering, 2025, 77, 108626
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Recent Progress on Semiconductor Heterogeneous Photocatalysts in Clean Energy Production and Environmental Remediation

Nahal Goodarzi, Zahra Ashrafi-Peyman, Elahe Khani and Alireza Z. Moshfegh

Catalysts, 2023, 13, 1102
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Hg0 to Hg2+ via photocatalysis by Bismuth-based photocatalysts: A review

Yifan Liu, Hengzhong Chen, Wenquan Zhou, Wencai Qian, Kai Huang, Xiaojing Liu, Mei Ma, Yang Ling, Jiang Wu and Fangqin Li

Journal of Environmental Chemical Engineering, 2025, 13, 116212
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Recent advances in bismuth oxyfluoride-based photocatalysts for energy and environmental remediation

Vinoth S and Pandikumar A

Materials Today Chemistry, 2024, 36, 101924
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Fabrication of polyaniline modified bismuth oxyhalide (X = Cl, I) composites for efficient photocatalytic degradation activity up to 730 nm

Han Zhang, Haoyu Zhang, Ruiduo Zhao and Shushu Huang

Journal of Environmental Chemical Engineering, 2026, 14, 120871
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Recent advances in bismuth oxyhalides BiOX (X = Cl, Br and I) based photocatalyst: Synthesis, properties, applications and looking beyond

Linlin Zhang, Xiaonan Sun, Rongrong Chen and Jun Wang

Renewable and Sustainable Energy Reviews, 2026, 226, 116249
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Construction of Fe3O4@ZIF-8@BiOX (X = Cl, Br, I) heterojunctions toward simultaneous removal of oxytetracycline and Cr(VI) by adsorption-photocatalysis

Menglu Wang, Bolong Liang, Shumin Lin, Zhe Zhao, Hongbin He, Xiliang Li and Shu-xuan Liang

Applied Surface Science, 2024, 657, 159791
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Precise structure-tailoring of multicomponent nanocatalysts enabled by continuous flow-controlled flash nanoprecipitation technique

Zhinan Fu, Yueping Bao, Yuhua Zhang, Zheng Yang, Lihui Zhou, Li Li, Sheng Dai, Xiao Hu and Xuhong Guo

Separation and Purification Technology, 2024, 351, 128008
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Constructing plasmonic bi-enhanced chrysanthemum-like Bi/BiOClBr microspheres for efficient photocatalytic decontamination of organic pollutants

Yankai Song, Zongqi Bao, Xianlong Ge, Shaohua Hu, Minfeng Meng and Yingying Gu

Applied Surface Science, 2024, 671, 160676
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Phosphorus heteroatom doped BiOCl as efficient catalyst for photo-piezocatalytic degradation of organic pollutant and unveiling the mechanism: Experiment and DFT calculation

Aize Hao, Xueer Ning, Xiaonan Liu, Lihui Zhan and Xiaojuan Qiu

Chemical Engineering Journal, 2024, 499, 155823
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The future of wastewater treatment: Recyclable BiOX/Bi2MoO6/Bi2S3 (X Cl, Br, I) photocatalyst for the effective degradation of ciprofloxacin

Muhammad Naeem, Muhammad Imran, Shoomaila Latif, Adnan Ashraf, Muhammad Aadil, Mujeeb Khan, Mohammed Rafiq H. Siddiqui and Syed Farooq Adil

Surfaces and Interfaces, 2026, 82, 108468
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Synthesis of a 3D Flower-Like BiOCl/Bi-MOF Heterostructure for High-Performance Removal of Rhodamine B and Tetracycline Hydrochloride

Vinh Huu Nguyen, Hoang Ai Le Pham, Taeyoon Lee and Trinh Duy Nguyen

Inorg. Chem., 2024, 63, 12027
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Construction of novel double S-scheme TiO2-x/BiOCl/BiCl3Br-CTA nanocomposites with quantum dot size for the photocatalytic degradation of pollutants

Arezou Saadati, Aziz Habibi-Yangjeh and Alireza Khataee

Advanced Powder Technology, 2025, 36, 104961
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Rational designed novel TiO2-x/Bi6Cr2O15/Bi quantum dots: Bi-based plasmonic photocatalysts for boosted detoxifying organic and inorganic wastewaters under visible light

Zahra Salmanzadeh-Jamadi, Aziz Habibi-Yangjeh, Alireza Khataee and Nurbolat Kudaibergenov

Surfaces and Interfaces, 2023, 41, 103199
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Kapok-derived biochar enhanced activation of bismuth oxyhalide for efficient seawater purification via oriented photoelectron migration

Qi Tang, Chongtai Wang, Jinyuan Liu, Xingwang Zhu, Daoxiong Wu, Huimin Han, Zheng Xie, Gaopeng Liu, Bin Wang, Paul K. Chu and Yingjie Hua

Chemical Engineering Science, 2026, 327, 123657
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Review On Strategies For the Design and Synthesis of Flower‐Like Bi2WO6 and BiOX (X=F, Cl, Br, I) Composites for Photocatalytic Environmental Remediation

Shubham Avinash Deshmukh, Selvaraj Suresh, Darpan Vijaykumar Bhuse, Subodh Uttamrao Raut, M. Vijaya Bhaskar Reddy and S. Ravichandran

ChemistrySelect, 2024, 9
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Engineered oxygen vacancies in NiCo2O4/BiOI heterostructures for enhanced photocatalytic pollutant degradation

Bavani Thirugnanam, Preeyanghaa Mani, Bader O. Almutairi, Kuppusamy Sathishkumar and Munusamy Settu

Environ Sci Pollut Res, 2024, 31, 66866
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In-situ engineered KBiFe2O5/BiOBr Z-scheme heterojunction photocatalyst for the pharmaceutical pollutant degradation and nitrogen fixation

Shijina Kottarathil, O.V. Abhinand and Kishore Sridharan

Applied Surface Science, 2026, 718, 164869
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