Spin-crossover iron(ii) complexes featuring boronic acid and boronic ester groups: synthesis and magnetic properties

Minghui Zhang, Frank W. Heinemann and Marat M. Khusniyarov

CrystEngComm, 2026
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Thermal and photoinduced spin-crossover of mononuclear FeII complexes based on bppCHO ligand

Qianqian Yang, Yin-Shan Meng, Tao Liu and Jinkui Tang

Dalton Trans., 2022, 51, 602
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The impact of whole-molecule disorder on spin-crossover in a family of isomorphous molecular crystals

Holly E. Sephton, Rhiannon L. Watson, Namrah Shahid, Hari Babu Vasili, Daniel L. Baker, Dipankar Saha, Izar Capel Berdiell, Christopher M. Pask, Oscar Cespedes and Malcolm A. Halcrow

Chem. Sci., 2025, 16, 9203
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A proficient multivariate approach for iron(ii) spin crossover behaviour modelling in the solid state

Lorenzo Marchi, Simone Fantuzzi, Andrea Cingolani, Alessandro Messori, Rita Mazzoni, Stefano Zacchini, Marina Cocchi and Luca Rigamonti

Dalton Trans., 2023, 52, 7684
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Two-step spin transition around room temperature in a FeIII complex

Jianfeng Wu, Mengtao Li, Qianqian Yang, Baoliang Zhang and Jinkui Tang

Dalton Trans., 2025, 54, 1231
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New iron(ii) spin-crossover metallomesogen with long aliphatic chain terminated by a CC bond

Shuting Liu, Zhenhua Zhu, Xiao-Lei Li and Jinkui Tang

Inorg. Chem. Front., 2022, 9, 267
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Structural Bifurcation in the High→Low‐Spin and Low→High‐Spin Phase Transitions Explains the Asymmetric Spin‐Crossover in [FeL2][BF4]2 (L=2,6‐Di{pyrazol‐1‐yl}isonicotinonitrile)

Ahmed Ahmed, Amy Hall, Hari Babu Vasili, Rafal Kulmaczewski, Alexander N. Kulak, Oscar Cespedes, Christopher M. Pask, Lee Brammer, Thomas M. Roseveare and Malcolm A. Halcrow

Angew Chem Int Ed, 2025, 64
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Di‐Iron(II) [2+2] Helicates of Bis‐(Dipyrazolylpyridine) Ligands: The Influence of the Ligand Linker Group on Spin State Properties

Rafal Kulmaczewski, Isaac T. Armstrong, Pip Catchpole, Emily S. J. Ratcliffe, Hari Babu Vasili, Stuart L. Warriner, Oscar Cespedes and Malcolm A. Halcrow

Chemistry A European J, 2023, 29
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Thermal and Unusual Light-Driven Cooperative Spin-State Switching in [Fe(bppI)2](ClO4)2 (bppI = 4-Iodo-2,6-di(pyrazol-1-yl)-pyridine) Probed by Single-Crystal Optical Spectroscopy

Chinmoy Das, Malcolm A. Halcrow, Denisa Coltuneac, Laurentiu Stoleriu and Pradip Chakraborty

J. Phys. Chem. C, 2025, 129, 19627
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Structural Insights into Hysteretic Spin‐Crossover in a Set of Iron(II)‐2,6‐bis(1H‐Pyrazol‐1‐yl)Pyridine) Complexes

Nithin Suryadevara, Asato Mizuno, Lea Spieker, Soma Salamon, Stephan Sleziona, André Maas, Erik Pollmann, Benoît Heinrich, Marika Schleberger, Heiko Wende, Senthil Kumar Kuppusamy and Mario Ruben

Chemistry A European J, 2022, 28
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Iron(II) Complexes of 4-(Alkyldisulfanyl)-2,6-di(pyrazolyl)pyridine Derivatives. Correlation of Spin-Crossover Cooperativity with Molecular Structure Following Single-Crystal-to-Single-Crystal Desolvation

Rafal Kulmaczewski, Laurence J. Kershaw Cook, Christopher M. Pask, Oscar Cespedes and Malcolm A. Halcrow

Crystal Growth & Design, 2022, 22, 1960
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An AIE-Active Fe(II) Complex Exhibiting Synergistic Spin-Crossover and Luminescent Properties

Jinjiang Wu, Qianqian Yang, Xiao-Lei Li, Zhenhua Zhu, Chen Zhao, Tao Liu and Jinkui Tang

Crystal Growth & Design, 2025, 25, 1276
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Guest-Induced Multistep to Single-Step Spin-Crossover Switching in a 2-D Hofmann-Like Framework with an Amide-Appended Ligand

Manan Ahmed, Kasun S. A. Arachchige, Zixi Xie, Jason R. Price, Jace Cruddas, Jack K. Clegg, Benjamin J. Powell, Cameron J. Kepert and Suzanne M. Neville

Inorg. Chem., 2022, 61, 11667
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Structural Bifurcation in the High→Low‐Spin and Low→High‐Spin Phase Transitions Explains the Asymmetric Spin‐Crossover in [FeL2][BF4]2 (L=2,6‐Di{pyrazol‐1‐yl}isonicotinonitrile)

Ahmed Ahmed, Amy Hall, Hari Babu Vasili, Rafal Kulmaczewski, Alexander N. Kulak, Oscar Cespedes, Christopher M. Pask, Lee Brammer, Thomas M. Roseveare and Malcolm A. Halcrow

Angewandte Chemie, 2025, 137
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Benchmarking Structures and UV–Vis Spectra of Iron Complexes Against Experimental Data

Renan R. Bertoloni, Vania M. Ramos, Ana Paula de Lima Batista and Antonio G. S. de Oliveira-Filho

J. Phys. Chem. A, 2025, 129, 10481
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Homometallic Intervalence Charge Transfer Band of Co(II/III) Induced by Phase Transitions in a Heterometallic Co–W Charge Transfer Photomagnet

Kazuki Nakamura, Koji Nakabayashi, Yuito Nosaka, Wakano Ota, Takashi Kikuchi and Shin‐ichi Ohkoshi

Small Science, 2026, 6
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Structures and Spin States of Iron(II) Complexes of Isomeric 2,6-Di(1,2,3-triazolyl)pyridine Ligands

Izar Capel Berdiell, Daniel J. Davies, Jack Woodworth, Rafal Kulmaczewski, Oscar Cespedes and Malcolm A. Halcrow

Inorg. Chem., 2021, 60, 14988
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Solvent Effects on the Spin Crossover Properties of Manganese (III) (sal‐N‐1,5,8,12) Complexes

Sheng‐Ze Zhao, Chang Liu, Hao‐Zhe Zhang, Hua‐Wei Zhou, Sen‐Yu Zhang, Chun‐Yan Qin, Yong‐hua Li, Chao Tang and Shi Wang

Eur J Inorg Chem, 2024, 27
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Spin-Crossover in Supramolecular Iron(II)–2,6-bis(1H-Pyrazol-1-yl)pyridine Complexes: Toward Spin-State Switchable Single-Molecule Junctions

Senthil Kumar Kuppusamy, Asato Mizuno, Amador García-Fuente, Sebastiaan van der Poel, Benoît Heinrich, Jaime Ferrer, Herre S. J. van der Zant and Mario Ruben

ACS Omega, 2022, 7, 13654
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Anion Effects on Spin Crossover Systems: From Supramolecular Chemistry to Magnetism

Sheng‐Ze Zhao, Hua‐Wei Zhou, Chun‐Yan Qin, Hao‐Zhe Zhang, Yong‐Hua Li, Masahiro Yamashita and Shi Wang

Chemistry A European J, 2023, 29
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