Synthesis and characterisation of alkaline earth bis(diphenylphosphano)metallocene complexes and heterobimetallic alkaline earth metal/platinum(ii) complexes [Ae(thf)x(η5-C5H4PPh2)2Pt(Me)2] (Ae = Ca, Sr, Ba)

Daisy P. Daniels, Glen B. Deacon, Dominique Harakat, Florian Jaroschik and Peter C. Junk

Dalton Trans., 2012, 41, 267
DOI: 10.1039/C1DT11324K

In crystallo homolytic cleavage of a terminal lanthanum(iii)–methyl bond by Cu Kα X-radiation forms a La(ii) complex

Cary R. Stennett, Makayla R. Luevano, Joseph W. Ziller and William J. Evans

Chem. Commun., 2026, 62, 547
DOI: 10.1039/D5CC04945H

Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII

Christian Ruspic, John R. Moss, Markus Schürmann and Sjoerd Harder

Angewandte Chemie, 2008, 120, 2151
DOI: 10.1002/ange.200705001

Lanthanide Terminal Hydride Complexes Bearing Two Sterically Demanding C5Me4SiMe3 Ligands. Synthesis, Structure, and Reactivity

Yasumasa Takenaka and Zhaomin Hou

Organometallics, 2009, 28, 5196
DOI: 10.1021/om900453j

The first examples of intermolecular weak (agostic) γ-methyl-metal interactions in organolanthanide complexes: The synthesis and X-ray structures of [{Yb(η-CP″)2}∞.] and [{Eu(η-CP″)2}∞] [CP″ C5H3(SiMe3)2-1,3]

Peter B. Hitchcock, Judith A.K. Howard, Michael F. Lappert and Sanjiv Prashar

Journal of Organometallic Chemistry, 1992, 437, 177
DOI: 10.1016/0022-328X(92)83442-K

The “solid angle sum rule”: A new ligand cone packing model of optimal applicability in organolanthanoid chemistry, part I

R.Dieter Fischer and Xing-Fu Li

Journal of the Less Common Metals, 1985, 112, 303
DOI: 10.1016/0022-5088(85)90038-4

Cation Charge Density and Precatalyst Selection in Group 2-Catalyzed Aminoalkene Hydroamination

Merle Arrowsmith, Mark R. Crimmin, Anthony G. M. Barrett, Michael S. Hill, Gabriele Kociok-Köhn and Panayiotis A. Procopiou

Organometallics, 2011, 30, 1493
DOI: 10.1021/om101063m

Ytterbium(III) Complexes Coordinated by Dianionic 1,4-Diazabutadiene Ligands

Boris G. Shestakov, Tatyana V. Mahrova, Joulia Larionova, Jêrome Long, Anton V. Cherkasov, Georgy K. Fukin, Konstantin A. Lyssenko, Wolfgang Scherer, Christoph Hauf, Tatiana V. Magdesieva, Oleg A. Levitskiy and Alexander A. Trifonov

Organometallics, 2015, 34, 1177
DOI: 10.1021/om501121s

Salt metathesis reactions of LnCl3 (Sc, Y vs. Sm, Yb) with potassium diphenylmethanide {[2,2′-(4-MeC6H3NMe2)2CH]K(THF)}2

Dmitry O. Khristolyubov, Dmitry M. Lyubov, Anton V. Cherkasov, Georgy K. Fukin and Alexander A. Trifonov

Mendeleev Communications, 2021, 31, 54
DOI: 10.1016/j.mencom.2021.01.016

Koordinationsverhältnisse in cyclopentadienylverbindungen II. Untersuchungen von M(C5H4CH3)2 · CH3OCH2CH2OCH3 mit MCa und Yb

A. Hammel, W. Schwarz and J. Weidlein

Journal of Organometallic Chemistry, 1989, 378, 347
DOI: 10.1016/0022-328X(89)85362-8

Organoyttrium-Catalyzed Sequential Cyclization/Silylation Reactions of Nitrogen-Heteroaromatic Dienes Demonstrating “Aryl-Directed” Regioselectivity

Gary A. Molander and Monika H. Schmitt

J. Org. Chem., 2000, 65, 3767
DOI: 10.1021/jo0000527

Reactions of alkali metal diphenylmethanides [(3,5-Bu2t-2-MeO-C6H2)2CH]M (M = Li, K) with LnCl3. The synthesis and structure of the complex [(3,5-Bu2t-2-MeO-C6H2)2CH]2ScCl

D. O. Khristolyubov, D. M. Lyubov, A. V. Cherkasov, G. K. Fukin and A. A. Trifonov

Russ Chem Bull, 2021, 70, 2110
DOI: 10.1007/s11172-021-3322-0

Syntheses and Physical Properties of Novel Optically Active Poly(ester−carbonate)s by Copolymerization of Substituted Trimethylene Carbonate with ε-Caprolactone and Their Biodegradation Behavior

Hajime Yasuda, Mohad-Serah Aludin, Naoyuki Kitamura, Mari Tanabe and Hiroyuki Sirahama

Macromolecules, 1999, 32, 6047
DOI: 10.1021/ma981904w

Four-electron reduction of benzene by a samarium(ii)-alkyl without the addition of external reducing agents

Georgia M. Richardson, Thayalan Rajeshkumar, Finlay M. Burke, Scott A. Cameron, Brooke D. Nicholls, Joanne E. Harvey, Robert A. Keyzers, Tane Butler, Simon Granville, Lujia Liu, Julien Langley, Li F. Lim, Nicholas Cox, Nicholas F. Chilton, Jamie Hicks, Nathaniel J. L. K. Davis, Laurent Maron and Mathew D. Anker

Nat. Chem., 2025, 17, 20
DOI: 10.1038/s41557-024-01688-6

Advances in the Chemistry of Organolanthanides

Mikhail N Bochkarev, G S Kalinina and L N Bochkarev

Russ. Chem. Rev., 1985, 54, 802
DOI: 10.1070/RC1985v054n08ABEH003112

Dinitrogen Reduction, Sulfur Reduction, and Isoprene Polymerization via Photochemical Activation of Trivalent Bis(cyclopentadienyl) Rare-Earth-Metal Allyl Complexes

Megan E. Fieser, Casey W. Johnson, Jefferson E. Bates, Joseph W. Ziller, Filipp Furche and William J. Evans

Organometallics, 2015, 34, 4387
DOI: 10.1021/acs.organomet.5b00613

Sterically Governed Redox Reactions. One-Electron Oxidation of Ytterbocenes by Diazabutadienes: Formation of Radical-Anionic Diazabutadiene vs Covalently Bonded Imino–Amido Ligand

Alexander A. Trifonov, Boris G. Shestakov, Konstantin A. Lyssenko, Joulia Larionova, Georgy K. Fukin and Anton V. Cherkasov

Organometallics, 2011, 30, 4882
DOI: 10.1021/om200429h

Lanthanide−Transition Metal Carbonyl Complexes: Condensation of Solvent-Separated Ion-Pair Compounds into Extended Structures

Pavel V. Poplaukhin, Xuenian Chen, Edward A. Meyers and Sheldon G. Shore

Inorg. Chem., 2006, 45, 10115
DOI: 10.1021/ic060756k

Dicyclopentadienylsamarium complexes with t-butyl substituents in the ring. Crystal and molecular structures of the solvate (η5-C5H3Bu2t)2Sm · OC4H8 and homoleptic ate complex [NaSm(η5:η2-C5H4But)3 · OC4H8]n

V.K. Bel'sky, Yu.K. Gunko, B.M. Bulychev, A.I. Sizov and G.L. Soloveichik

Journal of Organometallic Chemistry, 1990, 390, 35
DOI: 10.1016/0022-328X(90)85079-E

Catalytic Cyclization/Silylation of Dienes Containing 1,1-Disubstituted Olefins Using Organolanthanide and Group 3 Organometallic Complexes

Gary A. Molander, Eric D. Dowdy and Herbert Schumann

J. Org. Chem., 1998, 63, 3386
DOI: 10.1021/jo972359k

Lanthanide−Transition-Metal Carbonyl Complexes. 1. Syntheses and Structures of Ytterbium(II) Solvent-Separated Ion Pairs and Isocarbonyl Polymeric Arrays of Tetracarbonylcobaltate

Christine E. Plečnik, Shengming Liu, Jianping Liu, Xuenian Chen, Edward A. Meyers and Sheldon G. Shore

Inorg. Chem., 2002, 41, 4936
DOI: 10.1021/ic020254g

Synthesis and Reactions of [Cp*2Yb]2(μ-Me) and [Cp*2Yb]2(μ-Me)(Me) and Related Yb2(II, III) and Yb2(III, III) Compounds

Marc D. Walter, Phillip T. Matsunaga, Carol J. Burns, Laurent Maron and Richard A. Andersen

Organometallics, 2017, 36, 4564
DOI: 10.1021/acs.organomet.7b00384

Mechanochemical C–H bond activation: Synthesis of the tuckover hydrides, (C5Me5)2Ln(μ-H)(μ-η1:η5-CH2C5Me4)Ln(C5Me5) from solvent-free reactions of (C5Me5)2Ln(μ-Ph)2BPh2 with KC5Me5

David H. Woen, Jessica R.K. White, Joseph W. Ziller and William J. Evans

Journal of Organometallic Chemistry, 2019, 899, 120885
DOI: 10.1016/j.jorganchem.2019.120885

Half-Sandwich Lanthanide(III) Complexes Coordinated by Two α-Iminopyridine Radical Anions

Alexander A. Trifonov, Ivan D. Gudilenkov, Joulia Larionova, Carlos Luna, Georgy K. Fukin, Anton V. Cherkasov, Andrei I. Poddel’sky and Nikolai O. Druzhkov

Organometallics, 2009, 28, 6707
DOI: 10.1021/om9004143

New sandwich complexes of di- and trivalent ytterbium: Reduction of Yb(3+) by a bulky cyclooctatetraenyl dianion

Anja Edelmann, Cristian G. Hrib, Steffen Blaurock and Frank T. Edelmann

Journal of Organometallic Chemistry, 2010, 695, 2732
DOI: 10.1016/j.jorganchem.2010.07.035

Sodium naphthalenide reduction of 1,3–diphenyl–6–(tert-butyl) fulvene: Stabilizing Eu2+ with a sterically demanding ansa–ligand framework

Sonya K. Adas and Gary J. Balaich

Journal of Organometallic Chemistry, 2018, 857, 200
DOI: 10.1016/j.jorganchem.2017.12.008

Synthesis and molecular structure of (CH3Cp)2 Yb · DME and its catalytic activity for the polymerization of methyl methacrylate

Jiang Tao, Shen Qi, Lin Yonghua and Jin Songchun

Journal of Organometallic Chemistry, 1993, 450, 121
DOI: 10.1016/0022-328X(93)80147-4

Biodegradation of copolymers composed of optically active L‐lactide and (R)‐ or (S)‐1‐methyltrimethylene carbonate

Chikara Tsutsumi and Hajime Yasuda

J. Polym. Sci. A Polym. Chem., 2001, 39, 3916
DOI: 10.1002/pola.10035

Lanthanocene Catalysts in Selective Organic Synthesis

Gary A. Molander and Jan Antoinette C. Romero

Chem. Rev., 2002, 102, 2161
DOI: 10.1021/cr010291+

Dinitrogen Reduction via Photochemical Activation of Heteroleptic Tris(cyclopentadienyl) Rare-Earth Complexes

Megan E. Fieser, Jefferson E. Bates, Joseph W. Ziller, Filipp Furche and William J. Evans

J. Am. Chem. Soc., 2013, 135, 3804
DOI: 10.1021/ja400664s

Reaction of (C5Me5)2Yb(ER)(NH3) with Me3Al. Formation of (C5Me5)2Yb(AlMe4) and [(C5Me5)2Yb(ER)(AlMe3)2]2

David J. Berg and Richard A. Andersen

Organometallics, 2003, 22, 627
DOI: 10.1021/om020472h

Reduction of vanadium(II) to vanadium(O) by naphthaleneytterbium: synthesis and X-ray crystal structure of the two-dimensional multidecker complex [(η5-C5H5)V(μ-η6:η2-C10H8)Yb(THF)-(η5-C5H5)]n

Mikhail N. Bochkarev, Igor L. Fedushkin, Vladimir K. Cherkasov, Vladimir I. Nevodchikov, Herbert Schumann and Frank H. Görlitz

Inorganica Chimica Acta, 1992, 201, 69
DOI: 10.1016/S0020-1693(00)85004-5

Synthesis, X-ray Crystal Structure Determination, and NMR Spectroscopic Investigation of Two Homoleptic Four-Coordinate Lanthanide Complexes: Trivalent (tBu2P)2La[(μ-PtBu2)2Li(thf)] and Divalent Yb[(μ-PtBu2)2Li(thf)]2,1

Gerd W. Rabe, Jürgen Riede and Annette Schier

Inorg. Chem., 1996, 35, 40
DOI: 10.1021/ic950643t

Versatile Reactivity of a Lithium Tris(aryl)plumbate(II) Towards Organolanthanoid Compounds: Stable Lead–Lanthanoid–Metal Bonds or Redox Processes

Kornelia Zeckert, Jan Griebel, Reinhard Kirmse, Michael Weiß and Reinhard Denecke

Chemistry A European J, 2013, 19, 7718
DOI: 10.1002/chem.201300596

Samarium(III) compounds supported by the hydrotris(3,5-dimethyl-pyrazolyl)borate ligand: synthetic utility of the putative, reduction prone Sm(III)-hydrocarbyls, ‘(TpMe2)2SmR’

Irene Lopes, Bernardo Monteiro, Guanyang Lin, Ângela Domingos, Noémia Marques and Josef Takats

Journal of Organometallic Chemistry, 2001, 632, 119
DOI: 10.1016/S0022-328X(01)00855-5

Lanthanides and actinides annual Survey Covering the year 1980

Tobin J. Marks

Journal of Organometallic Chemistry, 1982, 227, 317
DOI: 10.1016/S0022-328X(00)92198-3

A New Heteroatom Coordination Promoted Homolysis of the Yb−N Bond. Synthesis and Structural Characterization of a New Class of Ytterbium(II) and Ytterbium(III) Complexes with Amido and Indenyl Ligands and Catalytic Activities of Ytterbium(II) Complexes

Enhong Sheng, Shaowu Wang, Gaosheng Yang, Shuangliu Zhou, Lin Cheng, Kehua Zhang and Zixiang Huang

Organometallics, 2003, 22, 684
DOI: 10.1021/om020562m

The organometallic Chemistry of the lanthanide elements in low oxidation states

William J. Evans

Polyhedron, 1987, 6, 803
DOI: 10.1016/S0277-5387(00)80921-3

Koordinationsverhältnisse in basenfreien tricyclopentadienyl-lanthanoid(III)-komplexen

Winfried Hinrichs, Detlef Melzer, Margrit Rehwoldt, Werner Jahn and R.Dieter Fischer

Journal of Organometallic Chemistry, 1983, 251, 299
DOI: 10.1016/S0022-328X(00)98774-6

Recent advances in organolanthanide chemistry

William J. Evans

Journal of Organometallic Chemistry, 1983, 250, 217
DOI: 10.1016/0022-328X(83)85052-9

The crystal and molecular structure of [η5-C5H3(SiMe3)2]2Yb(THF

Robin D. Rogers

Journal of Organometallic Chemistry, 1996, 512, 97
DOI: 10.1016/0022-328X(95)05878-S

Synthesis and Crystallographic Characterization of a Reduced Bimetallic Yttrium ansa-Metallocene Hydride Complex, [K(crypt)][(μ-CpAn)Y(μ-H)]2 (CpAn = Me2Si[C5H3(SiMe3)-3]2), with a 3.4 Å Yttrium–Yttrium Distance

Justin C. Wedal, Lauren M. Anderson-Sanchez, Megan T. Dumas, Colin A. Gould, María J. Beltrán-Leiva, Cristian Celis-Barros, Dayán Páez-Hernández, Joseph W. Ziller, Jeffrey R. Long and William J. Evans

J. Am. Chem. Soc., 2023, 145, 10730
DOI: 10.1021/jacs.3c01405

Activation of a CO bond by reaction of a tris(cyclopentadienyl)lanthanide complex with an alkali metal in dimethoxyethane (DME); crystal structures of [Ndη-C5H3(SiMe3)2-1,32(μ-OMe)2Li(DME)] and [{Ce(η-C5H3tBu2-1,3)2(μ-OMe)2]

Yurii K. Gun'ko, Peter B. Hitchcock and Michael F. Lappert

Journal of Organometallic Chemistry, 1995, 499, 213
DOI: 10.1016/0022-328X(95)00330-S

Synthesis and Characterization of the Europium Fullerides EuxC60 (x = 1−6)

A. S. Ginwalla, A. L. Balch, S. M. Kauzlarich, S. H. Irons, P. Klavins and R. N. Shelton

Chem. Mater., 1997, 9, 278
DOI: 10.1021/cm960358n

Unsolved dimeric organometallic samarium hydride versus solvated trisalkylborane supported monomeric hydride

Denise Baudry, Alain Dormond, Bruno Lachot, Marc Visseaux and Gaël Zucchi

Journal of Organometallic Chemistry, 1997, 547, 157
DOI: 10.1016/S0022-328X(97)00218-0

Synthesis and Structural Characterization of Divalent Ytterbium Complexes Supported byβ-Diketiminate Ligands and Their Catalytic Activity for the Polymerization of Methyl Methacrylate

Yingming Yao, Yong Zhang, Zhenqin Zhang, Qi Shen and Kaibei Yu

Organometallics, 2003, 22, 2876
DOI: 10.1021/om030136g

Synthesis and structure of bis(triphenylgermane)tetrakis(tetrahydrofuran)ytterbium

M.N. Bochkarev, I.M. Penyagina, L.N. Zakharov, Yu.F. Rad'kov, E.A. Fedorova, S.Ya. Khorshev and Yu.T. Struchkov

Journal of Organometallic Chemistry, 1989, 378, 363
DOI: 10.1016/0022-328X(89)85363-X

Bis(di-tert-butylcyclopentadienyl)ytterbium(ii). Synthesis and catalytic properties

S. Va. Knjazhanski, A. I. Sizov, A. V. Khsostov and B. M. Bulychev

Russ Chem Bull, 1996, 45, 1745
DOI: 10.1007/BF01431818

Synthesis, Characterization, and Structures of Divalent Europium and Ytterbium N,N-Dimethylaminodiboranates

Scott R. Daly and Gregory S. Girolami

Inorg. Chem., 2010, 49, 4578
DOI: 10.1021/ic100292u

Synthesis and Structural Characterization of Mixed-Valent Ytterbium and Europium Complexes Supported by a Phenoxy(quinolinyl)amide Ligand

Yinyin Jiang, Xi Zhu, Muzi Chen, Yaorong Wang, Yingming Yao, Bing Wu and Qi Shen

Organometallics, 2014, 33, 1972
DOI: 10.1021/om5000198

Remarkable Stability of Metallocenes with Superbulky Ligands: Spontaneous Reduction of SmIII to SmII

Christian Ruspic, John R. Moss, Markus Schürmann and Sjoerd Harder

Angew Chem Int Ed, 2008, 47, 2121
DOI: 10.1002/anie.200705001

Aspects of non-classical organolanthanide chemistry

M Cristina Cassani, Yurii K Gun'ko, Peter B Hitchcock, Alexander G Hulkes, Alexei V Khvostov, Michael F Lappert and Andrey V Protchenko

Journal of Organometallic Chemistry, 2002, 647, 71
DOI: 10.1016/S0022-328X(01)01484-X

Ytterbocenes as One‐ and Two‐Electron Reductants in their Reactions with Diazadienes: YbIII Mixed‐Ligand Bent‐Sandwich Complexes Containing a Dianion of Diazabutadiene

Alexander A. Trifonov, Ivan A. Borovkov, Elena A. Fedorova, Georgii K. Fukin, Joulia Larionova, Nikolai O. Druzhkov and Vladimir K. Cherkasov

Chemistry A European J, 2007, 13, 4981
DOI: 10.1002/chem.200601481