Issue 80, 2020

Synthesis of a B12–BODIPY dyad for B12-inspired photochemical transformations of a trichloromethylated organic compound

Abstract

A B12 complex–BODIPY dyad was synthesized by peripheral modification of cobalamin derivatives. The photophysical properties of the dyad were investigated by UV-vis, PL, and transient absorption spectroscopy. A visible light-driven dechlorination reaction of a trichlorinated organic compound, DDT, was reported. The dyad showed efficient catalysis for dechlorination under N2 with turnover numbers of over 220 for the reaction. One-pot syntheses of an ester and amide from DDT and benzotrichloride were also achieved using the dyad under air.

Graphical abstract: Synthesis of a B12–BODIPY dyad for B12-inspired photochemical transformations of a trichloromethylated organic compound

Supplementary files

Article information

Article type
Communication
Submitted
19 6月 2020
Accepted
04 9月 2020
First published
05 9月 2020

Chem. Commun., 2020,56, 11945-11948

Synthesis of a B12–BODIPY dyad for B12-inspired photochemical transformations of a trichloromethylated organic compound

Y. Anai, K. Shichijo, M. Fujitsuka, Y. Hisaeda and H. Shimakoshi, Chem. Commun., 2020, 56, 11945 DOI: 10.1039/D0CC04274A

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