Issue 2, 2018

Homologous Co3O4‖CoP nanowires grown on carbon cloth as a high-performance electrode pair for triclosan degradation and hydrogen evolution

Abstract

As a widely used antimicrobial agent in toothpastes and body washes for decades, triclosan (TCS) is causing great harm to the environment through wastewater. Herein, we used a two-electrode system to remove TCS comprising Co3O4 nanowires/carbon cloth (Co3O4 NWs/CC) as anode and CoP nanowires/carbon cloth (CoP NWs/CC) as cathode. At a constant current density of 10 mA cm−2, the degradation efficiency for TCS is 95% in 60 min and it is transformed into important chemical raw materials, including phenol, 1,2-dihydroxybenzene, and 2-phenoxyphenol. Subsequently, hydrogen is generated on the CoP NWs/CC cathode with Faradaic efficiency of nearly 100%. The synergetic effect of the superhydrophilic surfaces of the Co3O4 NWs/CC anode and the CoP NWs/CC cathode as well as the superaerophobicity of the cathode assures full contact of the electrolyte solution and the active materials and high-efficiency generation of H2 bubbles.

Graphical abstract: Homologous Co3O4‖CoP nanowires grown on carbon cloth as a high-performance electrode pair for triclosan degradation and hydrogen evolution

Supplementary files

Article information

Article type
Research Article
Submitted
18 11月 2017
Accepted
07 12月 2017
First published
11 12月 2017

Mater. Chem. Front., 2018,2, 323-330

Homologous Co3O4‖CoP nanowires grown on carbon cloth as a high-performance electrode pair for triclosan degradation and hydrogen evolution

C. Lyu, J. Zheng, R. Zhang, R. Zou, B. Liu and W. Zhou, Mater. Chem. Front., 2018, 2, 323 DOI: 10.1039/C7QM00533D

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