Issue 1, 2018

Unusual electromechanical response in rubrene single crystals

Abstract

Organic semiconductors are intensively studied as promising materials for the realisation of low-cost flexible electronic devices. The flexibility requirement implies either performance stability towards deformation, or conversely, detectable response to the deformation itself. The knowledge of the electromechanical response of organic semiconductors to external stresses is therefore not only interesting from a fundamental point of view, but also necessary for the development of real world applications. To this end, in this work we predict and measure the variation of charge carrier mobility in rubrene single crystals as a function of mechanical strain, applied selectively along the crystal axes. We find that strain induces simultaneous mobility changes along all three axes, and that in some cases the response is higher along directions orthogonal to the mechanical deformation. These variations cannot be explained by the modulation of intermolecular distances, but only by a more complex molecular reorganisation, which is particularly enhanced, in terms of response, by π-stacking and herringbone stacking. This microscopic knowledge of the relation between structural and mobility variations is essential for the interpretation of electromechanical measurements for crystalline organic semiconductors, and for the rational design of electronic devices.

Graphical abstract: Unusual electromechanical response in rubrene single crystals

Supplementary files

Article information

Article type
Communication
Submitted
30 6月 2017
Accepted
12 10月 2017
First published
12 10月 2017

Mater. Horiz., 2018,5, 41-50

Unusual electromechanical response in rubrene single crystals

M. Matta, M. J. Pereira, S. M. Gali, D. Thuau, Y. Olivier, A. Briseno, I. Dufour, C. Ayela, G. Wantz and L. Muccioli, Mater. Horiz., 2018, 5, 41 DOI: 10.1039/C7MH00489C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements