Issue 17, 2015

Inverted perovskite solar cells with inserted cross-linked electron-blocking interlayers for performance enhancement

Abstract

Perovskite solar cells fabricated via a solution process have drawn great attention due to their high power conversion efficiency (PCE). Here, we report cross-linked anode interlayers with solvent-resistance that reduce electron–hole recombination by blocking electrons for inverted type solution processed perovskite solar cells. The cross-linkable materials used are (N,N′-bis(4-(6-((3-ethyloxetan-3-yl)methoxy)-hexyloxy)phenyl)-N,N′-bis(4-methoxyphenyl)biphenyl-4,4′-diamine (QUPD) and N,N′-bis(4-(6-((3-ethyloxetan-3-yl)methoxy))-hexylphenyl)-N,N′-diphenyl-4,4′-diamine (OTPD)), which can be cross-linked in the presence of acid groups provided by diffusion from the underlying PEDOT:PSS layer. The resulting PCE shows an improvement from 9.93% (control device) to 13.06% (cross-linked QUPD (X-QUPD)) by about 3% under AM 1.5G 100 mW cm−2 illumination, which demonstrates that the introduction of cross-linked electron blocking interlayers is a promising way to enhance the performance of inverted type solution processed perovskite solar cells.

Graphical abstract: Inverted perovskite solar cells with inserted cross-linked electron-blocking interlayers for performance enhancement

Supplementary files

Article information

Article type
Paper
Submitted
25 2月 2015
Accepted
17 3月 2015
First published
18 3月 2015

J. Mater. Chem. A, 2015,3, 9291-9297

Inverted perovskite solar cells with inserted cross-linked electron-blocking interlayers for performance enhancement

H. Jhuo, P. Yeh, S. Liao, Y. Li, S. Sharma and S. Chen, J. Mater. Chem. A, 2015, 3, 9291 DOI: 10.1039/C5TA01479D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements