Issue 72, 2024

Tetraphenylpentalenide organolanthanide complexes

Abstract

The D2h symmetrical 1,3,4,6-tetraphenylpentalenide is an excellent ligand for the stabilisation of strongly coloured bis(pentalenide) LnIII sandwich complexes. These easily accessible compounds complement previously reported lanthanide organometallics and provide new opportunities to understand the roles of the f-orbitals in electronic structure and bonding.

Graphical abstract: Tetraphenylpentalenide organolanthanide complexes

Supplementary files

Article information

Article type
Communication
Submitted
27 5月 2024
Accepted
08 7月 2024
First published
12 7月 2024
This article is Open Access
Creative Commons BY license

Chem. Commun., 2024,60, 9749-9752

Tetraphenylpentalenide organolanthanide complexes

N. J. Katzer, M. Kaur, A. Sen, R. Nimaiyar, J. Autschbach, P. L. Arnold and U. Hintermair, Chem. Commun., 2024, 60, 9749 DOI: 10.1039/D4CC02570A

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